Detection of ozone gas using gold nanoislands and surface plasmon resonance

Gold nanoislands interact with gaseous ozone to produce a surface plasmon resonance shift, similarly to the interaction of ozone and gold nanoparticles in water. Gold nanoislands are produced by sputtering, which significantly simplifies the synthesis and produces controlled size for the gold nanois...

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Veröffentlicht in:Talanta (Oxford) 2009-12, Vol.80 (2), p.777-780
Hauptverfasser: Pisarenko, Aleksey N., Spendel, Wolfgang U., Taylor, Richard T., Brown, Jordan D., Cox, James. A., Pacey, Gilbert E.
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container_end_page 780
container_issue 2
container_start_page 777
container_title Talanta (Oxford)
container_volume 80
creator Pisarenko, Aleksey N.
Spendel, Wolfgang U.
Taylor, Richard T.
Brown, Jordan D.
Cox, James. A.
Pacey, Gilbert E.
description Gold nanoislands interact with gaseous ozone to produce a surface plasmon resonance shift, similarly to the interaction of ozone and gold nanoparticles in water. Gold nanoislands are produced by sputtering, which significantly simplifies the synthesis and produces controlled size for the gold nanoislands. The shift of surface plasmon resonance peak was monitored while gold nanoislands were exposed to variable concentration of gaseous ozone. The shift was then correlated with ozone concentration. Our current results indicate sensing gaseous ozone at concentration of as low as 20 μg/L is achievable. Gold nanoislands were reversed to their original wavelength and were able to cycle between the wavelengths as ozone was introduced and removed. Potentially, this system can be useful as a sensor that identifies the presence of ozone at low part-per-billion concentrations of ozone in gaseous media.
doi_str_mv 10.1016/j.talanta.2009.07.062
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subjects Analytical chemistry
Chemistry
Exact sciences and technology
General, instrumentation
Gold - chemistry
Gold nanoislands
Metal Nanoparticles - chemistry
Metal Nanoparticles - ultrastructure
Microscopy, Atomic Force
Microscopy, Electron, Scanning
Ozone - analysis
Ozone - chemistry
Ozone detection
Reproducibility of Results
Spectrophotometry
Surface plasmon resonance
Surface Plasmon Resonance - methods
title Detection of ozone gas using gold nanoislands and surface plasmon resonance
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