The Reaction of Thio Acids with Azides:  A New Mechanism and New Synthetic Applications

A new amide synthesis strategy based on a fundamental mechanistic revision of the reaction of thio acids and organic azides is presented. The data demonstrate that amines are not formed as intermediates in this reaction. Alternative mechanisms proceeding through a thiatriazoline intermediate are sug...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-07, Vol.125 (26), p.7754-7755
Hauptverfasser:	Shangguan, Ning, Katukojvala, Sreenivas, Greenberg, Rachel, Williams, Lawrence J
Format:	Artikel
Sprache:	eng
Schlagworte:	Amides - chemical synthesis Azides - chemistry Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms Sulfhydryl Compounds - chemistry
Online-Zugang:	Volltext
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