Palladium(II) Complexes of New Bulky Bidentate Phosphanes: Active and Highly Regioselective Catalysts for the Hydroxycarbonylation of Styrene

The synthesis of four new bulky bidentate phosphines that possess both tert‐butyl and trifluoromethylphenyl substituents is described. Symmetric ligands were readily obtained by alkylation of phosphidoboranes of the type Li[P(BH3)(tBu)(Ar)] with dihaloalkanes. Non‐symmetric ligands were prepared fro...

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Veröffentlicht in:	Chemistry : a European journal 2009-10, Vol.15 (40), p.10504-10513
Hauptverfasser:	Frew, Jamie J. R., Damian, Karen, Van Rensburg, Hendrik, Slawin, Alexandra M. Z., Tooze, Robert. P., Clarke, Matthew L.
Format:	Artikel
Sprache:	eng
Schlagworte:	carbonylation diphosphanes fluorinated phosphanes palladium reaction mechanisms
Online-Zugang:	Volltext
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