[O⁻NSR]TiCl₃-Catalyzed Copolymerization of Ethylene with Functionalized Olefins
All zipped up: Titanium complexes are designed as efficient catalysts for the copolymerization of ethylene with polar olefins, such as ω‐alkenol and ω‐alkenoic acid. An organophosphine catalyst can be zippered on the polyethylene (see scheme; TBS=tert‐butyldimethylsilyl, FG=functional group, MMAO=mo...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2009-01, Vol.48 (43), p.8099-8102 |
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| container_issue | 43 |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Yang, Xiao-Hong Liu, Chun-Rong Wang, Cong Sun, Xiu-Li Guo, Yang-Hui Wang, Xin-Ke Wang, Zheng Xie, Zuowei Tang, Yong |
| description | All zipped up: Titanium complexes are designed as efficient catalysts for the copolymerization of ethylene with polar olefins, such as ω‐alkenol and ω‐alkenoic acid. An organophosphine catalyst can be zippered on the polyethylene (see scheme; TBS=tert‐butyldimethylsilyl, FG=functional group, MMAO=modified methylaluminoxane) to form an efficient and recoverable initiator for [3+2] cycloaddition. |
| doi_str_mv | 10.1002/anie.200903334 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
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| language | eng |
| recordid | cdi_proquest_miscellaneous_734083387 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | alkenes copolymerization cycloaddition homogeneous catalysis titanium |
| title | [O⁻NSR]TiCl₃-Catalyzed Copolymerization of Ethylene with Functionalized Olefins |
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