Long-range intramolecular photoredox reaction via coupled charge and proton transfer of triplet excited anthraquinones mediated by water

The formal intramolecular photoredox reaction initially discovered for the parent 2-(hydroxymethyl)anthraquinone ( 1 ) has been extended to include analogs 3–6 in which the oxidizable benzyl alcoholgroup is significantly further away from the anthraquinone moiety. All of 3–6 undergo a clean and effi...

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Veröffentlicht in:Photochemical & photobiological sciences 2009-10, Vol.8 (10), p.1408-1415
Hauptverfasser: Hou, Yunyan, Huck, Lawrence A., Wan, Peter
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Sprache:eng
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