Beta-amidoaldehydes via oxazoline hydroformylation

Beta-amidoaldehydes via oxazoline hydroformylation

4-Substituted oxazolines, which are readily synthesized from naturally occurring alpha-amino acids, are converted efficiently and stereospecifically to beta-amidoaldehydes in the presence of synthesis gas and catalytic dicobalt octacarbonyl.

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Bibliographische Detailangaben
Veröffentlicht in:Chemical communications (Cambridge, England) England), 2009-01 (38), p.5704-5706
Hauptverfasser: Laitar, David S, Kramer, John W, Whiting, Bryan T, Lobkovsky, Emil B, Coates, Geoffrey W
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes - chemistry
Catalysis
Cobalt - chemistry
Gases - chemistry
Molecular Conformation
Oxazoles - chemistry
Stereoisomerism
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Beschreibung
Zusammenfassung:4-Substituted oxazolines, which are readily synthesized from naturally occurring alpha-amino acids, are converted efficiently and stereospecifically to beta-amidoaldehydes in the presence of synthesis gas and catalytic dicobalt octacarbonyl.
ISSN:1359-7345
1364-548X
DOI:10.1039/b913698c