Dramatic Advancements in the Saccharide to 5-(Chloromethyl)furfural Conversion Reaction
CMF from biomass ten times faster: Sugars, cellulose, and corn stover are converted into 5‐(chloromethyl)furfural (CMF) in only 3 h by digestion with hydrochloric acid in a closed, biphasic reactor at 80–100 °C in >80 % isolated yield. Under the same conditions, chitin gives a mixture of CMF and...
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| Veröffentlicht in: | ChemSusChem 2009-01, Vol.2 (9), p.859-861 |
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| creator | Mascal, Mark Nikitin, Edward B. |
| description | CMF from biomass ten times faster: Sugars, cellulose, and corn stover are converted into 5‐(chloromethyl)furfural (CMF) in only 3 h by digestion with hydrochloric acid in a closed, biphasic reactor at 80–100 °C in >80 % isolated yield. Under the same conditions, chitin gives a mixture of CMF and levulinic acid in a combined yield of 74 %. |
| doi_str_mv | 10.1002/cssc.200900136 |
| format | Article |
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| source | MEDLINE; Wiley Online Library Journals Frontfile Complete |
| subjects | Biomass carbohydrates Carbohydrates - chemistry cellulose Furaldehyde - analogs & derivatives Furaldehyde - chemistry renewable resources sustainable chemistry |
| title | Dramatic Advancements in the Saccharide to 5-(Chloromethyl)furfural Conversion Reaction |
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