On the XeF+/H2O System: Synthesis and Characterization of the Xenon(II) Oxide Fluoride Cation, FXeOXeFXeF

The reported synthesis of the H2OF+ cation as a product of the oxidative fluorination of H2O by [XeF][PnF6] (Pn = As, Sb) in HF solution has been reinvestigated. The system exhibits complex equilibria, producing two new Xe(II) compounds, [Xe3OF3][PnF6] and [H3O][PnF6]·2XeF2, refuting the original cl...

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Veröffentlicht in:	Journal of the American Chemical Society 2009-09, Vol.131 (37), p.13474-13489
Hauptverfasser:	Gerken, Michael, Moran, Matthew D, Mercier, Hélène P. A, Pointner, Bernard E, Schrobilgen, Gary J, Hoge, Berthold, Christe, Karl O, Boatz, Jerry A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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