Preformed π-Allyl Iron Complexes as Potent, Well-Defined Catalysts for the Allylic Substitution

Reanimation: Catalytically inactive π‐allyl iron complexes are “reanimated” upon addition of N‐heterocyclic carbene ligands such as 1,3‐dimesitylimidazolin‐2‐ylidene (SIMES). A comparison of stoichiometric and catalytic allylic alkylation reactions shows the π‐allyl mechanism to be active in this ca...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2009-01, Vol.48 (39), p.7251-7255
Hauptverfasser:	Holzwarth, Michael, Dieskau, André, Tabassam, Misbah, Plietker, Bernd
Format:	Artikel
Sprache:	eng
Schlagworte:	allyl ligands homogeneous catalysis iron nucleophiles regioselectivity
Online-Zugang:	Volltext
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