Unraveling Atomic Positions in an Oxide Spinel with Two Jahn−Teller Ions: Local Structure Investigation of CuMn2O4

At first sight, the quenched tetragonal spinel CuMn2O4 can be formulated with Cu2+ and Mn3+, implying that the tetrahedral site is Jahn−Teller (JT)-active Cu2+ and the octahedral site is JT-active Mn3+. High-resolution, high-momentum-transfer neutron scattering analysis suggests that the sample has...

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Veröffentlicht in:Journal of the American Chemical Society 2009-08, Vol.131 (32), p.11450-11457
Hauptverfasser: Shoemaker, Daniel P., Li, Jun, Seshadri, Ram
Format: Artikel
Sprache:eng
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