Synthesis and Characterization of the Dinuclear Polyhydrides [Os2H7(PPh i Pr2)4]+ and [Os2H6(PPh i Pr2)4]

The dinuclear osmium polyhydride [Os2H7(PPh i Pr2)4][HC(SO2CF3)2] (1) was synthesized by the protonation of [OsH6(PPh i Pr2)2] with bis(trifluoromethylsulfonyl)methane. Treatment with amine bases was not able to deprotonate 1, but reaction with potassium hydride gave the corresponding neutral polyhy...

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Veröffentlicht in:	Inorganic chemistry 2009-08, Vol.48 (16), p.7977-7983
Hauptverfasser:	Anderson, Bradley G., Hoyte, Sarah A., Spencer, John L.
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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