Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3

Aryl azide formation: The copper‐catalyzed coupling reaction of boronic esters and acids with TMSN3 have been presented as a highly efficient, simple, broadly applicable, and less hazardous methodology for the practical synthesis of aryl azides with structural diversity (see scheme).

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Veröffentlicht in:	Chemistry : a European journal 2010-07, Vol.16 (27), p.7969-7972
Hauptverfasser:	Li, Yu, Gao, Lian-Xun, Han, Fu-She
Format:	Artikel
Sprache:	eng
Schlagworte:	aryl azides boronic acids boronic esters Chemistry copper cross-coupling
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description	Aryl azide formation: The copper‐catalyzed coupling reaction of boronic esters and acids with TMSN3 have been presented as a highly efficient, simple, broadly applicable, and less hazardous methodology for the practical synthesis of aryl azides with structural diversity (see scheme).
doi_str_mv	10.1002/chem.201000971
format	Article
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subjects	aryl azides boronic acids boronic esters Chemistry copper cross-coupling
title	Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3
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