Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands
The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh(2))(2)] (M = Ni, Pd, Pt; 2-PyPPh(2) = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh(2))(2)(SnCl(2))](+) where the...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2010-01, Vol.39 (9), p.2423-2427 |
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| container_end_page | 2427 |
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| container_issue | 9 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 39 |
| creator | Cabon, Yves Kleijn, Henk Siegler, Maxime A Spek, Anthony L Klein Gebbink, Robertus J M Deelman, Berth-Jan |
| description | The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh(2))(2)] (M = Ni, Pd, Pt; 2-PyPPh(2) = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh(2))(2)(SnCl(2))](+) where the M-Sn bond is bridged by two head-to-head coordinated 2-PyPPh(2) ligands. The formation of such species instead of the classical neutral trichlorostannyl derivatives [M(X)(SnCl(3))(2-PyPPh(2))(2)] offers a new insight on the specific effect of the SnCl(2) cocatalyst in group 10 metal catalyzed transformations. |
| doi_str_mv | 10.1039/b924783c |
| format | Article |
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The formation of such species instead of the classical neutral trichlorostannyl derivatives [M(X)(SnCl(3))(2-PyPPh(2))(2)] offers a new insight on the specific effect of the SnCl(2) cocatalyst in group 10 metal catalyzed transformations.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/b924783c</identifier><identifier>PMID: 20162217</identifier><language>eng</language><publisher>England</publisher><subject>Access bridges ; Bonding ; Cationic ; Crystallography, X-Ray ; Derivatives ; Dichlorides ; Ligands ; Models, Molecular ; Molecular Structure ; Nickel - chemistry ; Organometallic Compounds - chemical synthesis ; Organometallic Compounds - chemistry ; Palladium - chemistry ; Phosphines - chemistry ; Platinum - chemistry ; Precursors ; Pyridines - chemistry ; Tin Compounds - chemistry ; Transformations</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2010-01, Vol.39 (9), p.2423-2427</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-49405fc7eeb3a22b7815382a1dd02ba52b341ab08c13a43e17cf379af3d0c0ab3</citedby><cites>FETCH-LOGICAL-c348t-49405fc7eeb3a22b7815382a1dd02ba52b341ab08c13a43e17cf379af3d0c0ab3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20162217$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Cabon, Yves</creatorcontrib><creatorcontrib>Kleijn, Henk</creatorcontrib><creatorcontrib>Siegler, Maxime A</creatorcontrib><creatorcontrib>Spek, Anthony L</creatorcontrib><creatorcontrib>Klein Gebbink, Robertus J M</creatorcontrib><creatorcontrib>Deelman, Berth-Jan</creatorcontrib><title>Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh(2))(2)] (M = Ni, Pd, Pt; 2-PyPPh(2) = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh(2))(2)(SnCl(2))](+) where the M-Sn bond is bridged by two head-to-head coordinated 2-PyPPh(2) ligands. The formation of such species instead of the classical neutral trichlorostannyl derivatives [M(X)(SnCl(3))(2-PyPPh(2))(2)] offers a new insight on the specific effect of the SnCl(2) cocatalyst in group 10 metal catalyzed transformations.</description><subject>Access bridges</subject><subject>Bonding</subject><subject>Cationic</subject><subject>Crystallography, X-Ray</subject><subject>Derivatives</subject><subject>Dichlorides</subject><subject>Ligands</subject><subject>Models, Molecular</subject><subject>Molecular Structure</subject><subject>Nickel - chemistry</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - chemistry</subject><subject>Palladium - chemistry</subject><subject>Phosphines - chemistry</subject><subject>Platinum - chemistry</subject><subject>Precursors</subject><subject>Pyridines - chemistry</subject><subject>Tin Compounds - chemistry</subject><subject>Transformations</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtv1TAQhS0EoqUg9Rcg72BB6HjsxMmyKk-pEpuyjvyY3OvKiUN8I5Gu-Om4oi27djVHmm_OjOYwdirgowDZndkOlW6le8aOhdK66lCq5w8amyP2KudrAESo8SU7QhANotDH7M-n4PYxLSkfzDRtkSbiLo1zpN-UeRr4bknrzAXwkQ4m5g_c8HUKv1biNk0-TDs-Jk-8jNsQww15bjdul-B3tz2s5q3oLfow76n4z_uU530oW2LYmcnn1-zFUHzpzV09YT-_fL66-FZd_vj6_eL8snJStYdKdQrqwWkiKw2i1a2oZYtGeA9oTY1WKmEstE5IoyQJ7QapOzNIDw6MlSfs3T_feUnl-nzox5AdxWgmSmvutZSdQtCqkO8fJYWWAC02rX4aBdE1CE0t_6Ou_DovNPTzEkazbAXqb0Ps70Ms6Ns719WO5B_A-9TkX7CCmF8</recordid><startdate>20100101</startdate><enddate>20100101</enddate><creator>Cabon, Yves</creator><creator>Kleijn, Henk</creator><creator>Siegler, Maxime A</creator><creator>Spek, Anthony L</creator><creator>Klein Gebbink, Robertus J M</creator><creator>Deelman, Berth-Jan</creator><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7SR</scope><scope>8BQ</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>20100101</creationdate><title>Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands</title><author>Cabon, Yves ; Kleijn, Henk ; Siegler, Maxime A ; Spek, Anthony L ; Klein Gebbink, Robertus J M ; Deelman, Berth-Jan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c348t-49405fc7eeb3a22b7815382a1dd02ba52b341ab08c13a43e17cf379af3d0c0ab3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Access bridges</topic><topic>Bonding</topic><topic>Cationic</topic><topic>Crystallography, X-Ray</topic><topic>Derivatives</topic><topic>Dichlorides</topic><topic>Ligands</topic><topic>Models, Molecular</topic><topic>Molecular Structure</topic><topic>Nickel - chemistry</topic><topic>Organometallic Compounds - chemical synthesis</topic><topic>Organometallic Compounds - chemistry</topic><topic>Palladium - chemistry</topic><topic>Phosphines - chemistry</topic><topic>Platinum - chemistry</topic><topic>Precursors</topic><topic>Pyridines - chemistry</topic><topic>Tin Compounds - chemistry</topic><topic>Transformations</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cabon, Yves</creatorcontrib><creatorcontrib>Kleijn, Henk</creatorcontrib><creatorcontrib>Siegler, Maxime A</creatorcontrib><creatorcontrib>Spek, Anthony L</creatorcontrib><creatorcontrib>Klein Gebbink, Robertus J M</creatorcontrib><creatorcontrib>Deelman, Berth-Jan</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cabon, Yves</au><au>Kleijn, Henk</au><au>Siegler, Maxime A</au><au>Spek, Anthony L</au><au>Klein Gebbink, Robertus J M</au><au>Deelman, Berth-Jan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2010-01-01</date><risdate>2010</risdate><volume>39</volume><issue>9</issue><spage>2423</spage><epage>2427</epage><pages>2423-2427</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>The reaction of tin dichloride with catalytically-relevant group 10 metal precursors [M(Cl)(X)(2-PyPPh(2))(2)] (M = Ni, Pd, Pt; 2-PyPPh(2) = 2-pyridyldiphenylphosphine; X = Cl, Me) provides easy access to unprecedented cationic dichlorostannylene complexes [M(X)(2-PyPPh(2))(2)(SnCl(2))](+) where the M-Sn bond is bridged by two head-to-head coordinated 2-PyPPh(2) ligands. The formation of such species instead of the classical neutral trichlorostannyl derivatives [M(X)(SnCl(3))(2-PyPPh(2))(2)] offers a new insight on the specific effect of the SnCl(2) cocatalyst in group 10 metal catalyzed transformations.</abstract><cop>England</cop><pmid>20162217</pmid><doi>10.1039/b924783c</doi><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2010-01, Vol.39 (9), p.2423-2427 |
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| language | eng |
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| source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Access bridges Bonding Cationic Crystallography, X-Ray Derivatives Dichlorides Ligands Models, Molecular Molecular Structure Nickel - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Palladium - chemistry Phosphines - chemistry Platinum - chemistry Precursors Pyridines - chemistry Tin Compounds - chemistry Transformations |
| title | Dichlorostannylene complexes of group 10 metals, a unique bonding mode stabilized by bridging 2-pyridyldiphenylphosphine ligands |
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