Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene
A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of...
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Veröffentlicht in: | Journal of hazardous materials 2010-03, Vol.175 (1), p.1031-1036 |
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creator | Ramanjaneyulu, P.S. Singh, Parminder Sayi, Y.S. Chawla, H.M. Ramakumar, K.L. |
description | A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10
−5–10
−1
M CsCl was obtained. The Nernstian slope of the response was 56
mV per decade for Cs with a response time less than 20
s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb
+, K
+, Na
+, NH
4
+, Sr
2+, Ba
2+, Ca
2+, Mg
2+, Cu
2+, Pb
2+, Zn
2+, Ni
2+ and Ce
3+. The response of ISE for Cs
+ was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry. |
doi_str_mv | 10.1016/j.jhazmat.2009.10.113 |
format | Article |
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−5–10
−1
M CsCl was obtained. The Nernstian slope of the response was 56
mV per decade for Cs with a response time less than 20
s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb
+, K
+, Na
+, NH
4
+, Sr
2+, Ba
2+, Ca
2+, Mg
2+, Cu
2+, Pb
2+, Zn
2+, Ni
2+ and Ce
3+. The response of ISE for Cs
+ was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2009.10.113</identifier><identifier>PMID: 19942345</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Applied sciences ; Calixarene azo compound ; Calixarenes - chemistry ; Cesium - chemistry ; Cesium ion selective electrode ; Chlorides - chemistry ; Electrochemistry - methods ; Exact sciences and technology ; Hydrogen-Ion Concentration ; Ion-Selective Electrodes ; Ions ; Membranes, Artificial ; Phenols - chemistry ; Plasticizers - chemistry ; Pollution ; Poly(vinyl chloride) membrane electrode ; Polyvinyl Chloride - chemistry ; Potentiometry ; Radioactive Waste - analysis ; Radioactive waste streams ; Radioactive wastes ; Rivers ; Spectrophotometry, Atomic - methods ; Wastes ; Water Pollutants, Chemical - analysis</subject><ispartof>Journal of hazardous materials, 2010-03, Vol.175 (1), p.1031-1036</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>(c) 2009 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</citedby><cites>FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jhazmat.2009.10.113$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=22590944$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19942345$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramanjaneyulu, P.S.</creatorcontrib><creatorcontrib>Singh, Parminder</creatorcontrib><creatorcontrib>Sayi, Y.S.</creatorcontrib><creatorcontrib>Chawla, H.M.</creatorcontrib><creatorcontrib>Ramakumar, K.L.</creatorcontrib><title>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10
−5–10
−1
M CsCl was obtained. The Nernstian slope of the response was 56
mV per decade for Cs with a response time less than 20
s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb
+, K
+, Na
+, NH
4
+, Sr
2+, Ba
2+, Ca
2+, Mg
2+, Cu
2+, Pb
2+, Zn
2+, Ni
2+ and Ce
3+. The response of ISE for Cs
+ was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</description><subject>Applied sciences</subject><subject>Calixarene azo compound</subject><subject>Calixarenes - chemistry</subject><subject>Cesium - chemistry</subject><subject>Cesium ion selective electrode</subject><subject>Chlorides - chemistry</subject><subject>Electrochemistry - methods</subject><subject>Exact sciences and technology</subject><subject>Hydrogen-Ion Concentration</subject><subject>Ion-Selective Electrodes</subject><subject>Ions</subject><subject>Membranes, Artificial</subject><subject>Phenols - chemistry</subject><subject>Plasticizers - chemistry</subject><subject>Pollution</subject><subject>Poly(vinyl chloride) membrane electrode</subject><subject>Polyvinyl Chloride - chemistry</subject><subject>Potentiometry</subject><subject>Radioactive Waste - analysis</subject><subject>Radioactive waste streams</subject><subject>Radioactive wastes</subject><subject>Rivers</subject><subject>Spectrophotometry, Atomic - methods</subject><subject>Wastes</subject><subject>Water Pollutants, Chemical - analysis</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc1u1DAQgC0EokvhEUC5IFqpXvyf-FShqrSVKnGBE0KWY0-0XuVnsTdV0xPP1EfiSfDuRvTYk-2Zb-yZzwi9p2RJCVWf18v1yj50drtkhOjlLkz5C7SgVckx51y9RAvCicC80uIIvUlpTQihpRSv0RHVWjAu5AKNN0NfJGjBbcMdFPtNHDwUzRALBymMXVHbBL7InMQn4u-fR9yHzGxW0E-tfRhOmTxjJa5DOmF4kxNTO9xPp0ydsQr7sJp8zGdn23D_U_yyEXp4i141tk3wbl6P0Y-vl98vrvHtt6ubiy-32Akut1gxxpQjVFhW8lqWjS1rsKVySnBLCXiQihAlpPNN43fDOVFpWpGy8V5xzY_Rp8O9ua3fI6St6UJy0La2h2FMpuRcMyX3pDyQLg4pRWjMJobOxslQYnbCzdrMws1O-D5Mea77ML8w1h34p6rZcAY-zoBN2UETbe9C-s8xJjXRQmTu_MBB9nEXIJrkAvQOfIj5T4wfwjOt_APoAKFh</recordid><startdate>20100315</startdate><enddate>20100315</enddate><creator>Ramanjaneyulu, P.S.</creator><creator>Singh, Parminder</creator><creator>Sayi, Y.S.</creator><creator>Chawla, H.M.</creator><creator>Ramakumar, K.L.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100315</creationdate><title>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</title><author>Ramanjaneyulu, P.S. ; Singh, Parminder ; Sayi, Y.S. ; Chawla, H.M. ; Ramakumar, K.L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Calixarene azo compound</topic><topic>Calixarenes - chemistry</topic><topic>Cesium - chemistry</topic><topic>Cesium ion selective electrode</topic><topic>Chlorides - chemistry</topic><topic>Electrochemistry - methods</topic><topic>Exact sciences and technology</topic><topic>Hydrogen-Ion Concentration</topic><topic>Ion-Selective Electrodes</topic><topic>Ions</topic><topic>Membranes, Artificial</topic><topic>Phenols - chemistry</topic><topic>Plasticizers - chemistry</topic><topic>Pollution</topic><topic>Poly(vinyl chloride) membrane electrode</topic><topic>Polyvinyl Chloride - chemistry</topic><topic>Potentiometry</topic><topic>Radioactive Waste - analysis</topic><topic>Radioactive waste streams</topic><topic>Radioactive wastes</topic><topic>Rivers</topic><topic>Spectrophotometry, Atomic - methods</topic><topic>Wastes</topic><topic>Water Pollutants, Chemical - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramanjaneyulu, P.S.</creatorcontrib><creatorcontrib>Singh, Parminder</creatorcontrib><creatorcontrib>Sayi, Y.S.</creatorcontrib><creatorcontrib>Chawla, H.M.</creatorcontrib><creatorcontrib>Ramakumar, K.L.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramanjaneyulu, P.S.</au><au>Singh, Parminder</au><au>Sayi, Y.S.</au><au>Chawla, H.M.</au><au>Ramakumar, K.L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2010-03-15</date><risdate>2010</risdate><volume>175</volume><issue>1</issue><spage>1031</spage><epage>1036</epage><pages>1031-1036</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10
−5–10
−1
M CsCl was obtained. The Nernstian slope of the response was 56
mV per decade for Cs with a response time less than 20
s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb
+, K
+, Na
+, NH
4
+, Sr
2+, Ba
2+, Ca
2+, Mg
2+, Cu
2+, Pb
2+, Zn
2+, Ni
2+ and Ce
3+. The response of ISE for Cs
+ was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>19942345</pmid><doi>10.1016/j.jhazmat.2009.10.113</doi><tpages>6</tpages></addata></record> |
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source | MEDLINE; Elsevier ScienceDirect Journals |
subjects | Applied sciences Calixarene azo compound Calixarenes - chemistry Cesium - chemistry Cesium ion selective electrode Chlorides - chemistry Electrochemistry - methods Exact sciences and technology Hydrogen-Ion Concentration Ion-Selective Electrodes Ions Membranes, Artificial Phenols - chemistry Plasticizers - chemistry Pollution Poly(vinyl chloride) membrane electrode Polyvinyl Chloride - chemistry Potentiometry Radioactive Waste - analysis Radioactive waste streams Radioactive wastes Rivers Spectrophotometry, Atomic - methods Wastes Water Pollutants, Chemical - analysis |
title | Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene |
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