Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene

A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of hazardous materials 2010-03, Vol.175 (1), p.1031-1036
Hauptverfasser: Ramanjaneyulu, P.S., Singh, Parminder, Sayi, Y.S., Chawla, H.M., Ramakumar, K.L.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1036
container_issue 1
container_start_page 1031
container_title Journal of hazardous materials
container_volume 175
creator Ramanjaneyulu, P.S.
Singh, Parminder
Sayi, Y.S.
Chawla, H.M.
Ramakumar, K.L.
description A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10 −5–10 −1 M CsCl was obtained. The Nernstian slope of the response was 56 mV per decade for Cs with a response time less than 20 s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb +, K +, Na +, NH 4 +, Sr 2+, Ba 2+, Ca 2+, Mg 2+, Cu 2+, Pb 2+, Zn 2+, Ni 2+ and Ce 3+. The response of ISE for Cs + was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.
doi_str_mv 10.1016/j.jhazmat.2009.10.113
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_733926539</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S0304389409017646</els_id><sourcerecordid>733926539</sourcerecordid><originalsourceid>FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</originalsourceid><addsrcrecordid>eNqFkc1u1DAQgC0EokvhEUC5IFqpXvyf-FShqrSVKnGBE0KWY0-0XuVnsTdV0xPP1EfiSfDuRvTYk-2Zb-yZzwi9p2RJCVWf18v1yj50drtkhOjlLkz5C7SgVckx51y9RAvCicC80uIIvUlpTQihpRSv0RHVWjAu5AKNN0NfJGjBbcMdFPtNHDwUzRALBymMXVHbBL7InMQn4u-fR9yHzGxW0E-tfRhOmTxjJa5DOmF4kxNTO9xPp0ydsQr7sJp8zGdn23D_U_yyEXp4i141tk3wbl6P0Y-vl98vrvHtt6ubiy-32Akut1gxxpQjVFhW8lqWjS1rsKVySnBLCXiQihAlpPNN43fDOVFpWpGy8V5xzY_Rp8O9ua3fI6St6UJy0La2h2FMpuRcMyX3pDyQLg4pRWjMJobOxslQYnbCzdrMws1O-D5Mea77ML8w1h34p6rZcAY-zoBN2UETbe9C-s8xJjXRQmTu_MBB9nEXIJrkAvQOfIj5T4wfwjOt_APoAKFh</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733926539</pqid></control><display><type>article</type><title>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</title><source>MEDLINE</source><source>Elsevier ScienceDirect Journals</source><creator>Ramanjaneyulu, P.S. ; Singh, Parminder ; Sayi, Y.S. ; Chawla, H.M. ; Ramakumar, K.L.</creator><creatorcontrib>Ramanjaneyulu, P.S. ; Singh, Parminder ; Sayi, Y.S. ; Chawla, H.M. ; Ramakumar, K.L.</creatorcontrib><description>A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10 −5–10 −1 M CsCl was obtained. The Nernstian slope of the response was 56 mV per decade for Cs with a response time less than 20 s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb +, K +, Na +, NH 4 +, Sr 2+, Ba 2+, Ca 2+, Mg 2+, Cu 2+, Pb 2+, Zn 2+, Ni 2+ and Ce 3+. The response of ISE for Cs + was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</description><identifier>ISSN: 0304-3894</identifier><identifier>EISSN: 1873-3336</identifier><identifier>DOI: 10.1016/j.jhazmat.2009.10.113</identifier><identifier>PMID: 19942345</identifier><identifier>CODEN: JHMAD9</identifier><language>eng</language><publisher>Kidlington: Elsevier B.V</publisher><subject>Applied sciences ; Calixarene azo compound ; Calixarenes - chemistry ; Cesium - chemistry ; Cesium ion selective electrode ; Chlorides - chemistry ; Electrochemistry - methods ; Exact sciences and technology ; Hydrogen-Ion Concentration ; Ion-Selective Electrodes ; Ions ; Membranes, Artificial ; Phenols - chemistry ; Plasticizers - chemistry ; Pollution ; Poly(vinyl chloride) membrane electrode ; Polyvinyl Chloride - chemistry ; Potentiometry ; Radioactive Waste - analysis ; Radioactive waste streams ; Radioactive wastes ; Rivers ; Spectrophotometry, Atomic - methods ; Wastes ; Water Pollutants, Chemical - analysis</subject><ispartof>Journal of hazardous materials, 2010-03, Vol.175 (1), p.1031-1036</ispartof><rights>2009 Elsevier B.V.</rights><rights>2015 INIST-CNRS</rights><rights>(c) 2009 Elsevier B.V. All rights reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</citedby><cites>FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jhazmat.2009.10.113$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,45974</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&amp;idt=22590944$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/19942345$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Ramanjaneyulu, P.S.</creatorcontrib><creatorcontrib>Singh, Parminder</creatorcontrib><creatorcontrib>Sayi, Y.S.</creatorcontrib><creatorcontrib>Chawla, H.M.</creatorcontrib><creatorcontrib>Ramakumar, K.L.</creatorcontrib><title>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</title><title>Journal of hazardous materials</title><addtitle>J Hazard Mater</addtitle><description>A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10 −5–10 −1 M CsCl was obtained. The Nernstian slope of the response was 56 mV per decade for Cs with a response time less than 20 s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb +, K +, Na +, NH 4 +, Sr 2+, Ba 2+, Ca 2+, Mg 2+, Cu 2+, Pb 2+, Zn 2+, Ni 2+ and Ce 3+. The response of ISE for Cs + was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</description><subject>Applied sciences</subject><subject>Calixarene azo compound</subject><subject>Calixarenes - chemistry</subject><subject>Cesium - chemistry</subject><subject>Cesium ion selective electrode</subject><subject>Chlorides - chemistry</subject><subject>Electrochemistry - methods</subject><subject>Exact sciences and technology</subject><subject>Hydrogen-Ion Concentration</subject><subject>Ion-Selective Electrodes</subject><subject>Ions</subject><subject>Membranes, Artificial</subject><subject>Phenols - chemistry</subject><subject>Plasticizers - chemistry</subject><subject>Pollution</subject><subject>Poly(vinyl chloride) membrane electrode</subject><subject>Polyvinyl Chloride - chemistry</subject><subject>Potentiometry</subject><subject>Radioactive Waste - analysis</subject><subject>Radioactive waste streams</subject><subject>Radioactive wastes</subject><subject>Rivers</subject><subject>Spectrophotometry, Atomic - methods</subject><subject>Wastes</subject><subject>Water Pollutants, Chemical - analysis</subject><issn>0304-3894</issn><issn>1873-3336</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkc1u1DAQgC0EokvhEUC5IFqpXvyf-FShqrSVKnGBE0KWY0-0XuVnsTdV0xPP1EfiSfDuRvTYk-2Zb-yZzwi9p2RJCVWf18v1yj50drtkhOjlLkz5C7SgVckx51y9RAvCicC80uIIvUlpTQihpRSv0RHVWjAu5AKNN0NfJGjBbcMdFPtNHDwUzRALBymMXVHbBL7InMQn4u-fR9yHzGxW0E-tfRhOmTxjJa5DOmF4kxNTO9xPp0ydsQr7sJp8zGdn23D_U_yyEXp4i141tk3wbl6P0Y-vl98vrvHtt6ubiy-32Akut1gxxpQjVFhW8lqWjS1rsKVySnBLCXiQihAlpPNN43fDOVFpWpGy8V5xzY_Rp8O9ua3fI6St6UJy0La2h2FMpuRcMyX3pDyQLg4pRWjMJobOxslQYnbCzdrMws1O-D5Mea77ML8w1h34p6rZcAY-zoBN2UETbe9C-s8xJjXRQmTu_MBB9nEXIJrkAvQOfIj5T4wfwjOt_APoAKFh</recordid><startdate>20100315</startdate><enddate>20100315</enddate><creator>Ramanjaneyulu, P.S.</creator><creator>Singh, Parminder</creator><creator>Sayi, Y.S.</creator><creator>Chawla, H.M.</creator><creator>Ramakumar, K.L.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100315</creationdate><title>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</title><author>Ramanjaneyulu, P.S. ; Singh, Parminder ; Sayi, Y.S. ; Chawla, H.M. ; Ramakumar, K.L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-62226c014a273b57fa7bea76c643a10ede5600645cdffd0175c4891807fdd6393</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Applied sciences</topic><topic>Calixarene azo compound</topic><topic>Calixarenes - chemistry</topic><topic>Cesium - chemistry</topic><topic>Cesium ion selective electrode</topic><topic>Chlorides - chemistry</topic><topic>Electrochemistry - methods</topic><topic>Exact sciences and technology</topic><topic>Hydrogen-Ion Concentration</topic><topic>Ion-Selective Electrodes</topic><topic>Ions</topic><topic>Membranes, Artificial</topic><topic>Phenols - chemistry</topic><topic>Plasticizers - chemistry</topic><topic>Pollution</topic><topic>Poly(vinyl chloride) membrane electrode</topic><topic>Polyvinyl Chloride - chemistry</topic><topic>Potentiometry</topic><topic>Radioactive Waste - analysis</topic><topic>Radioactive waste streams</topic><topic>Radioactive wastes</topic><topic>Rivers</topic><topic>Spectrophotometry, Atomic - methods</topic><topic>Wastes</topic><topic>Water Pollutants, Chemical - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ramanjaneyulu, P.S.</creatorcontrib><creatorcontrib>Singh, Parminder</creatorcontrib><creatorcontrib>Sayi, Y.S.</creatorcontrib><creatorcontrib>Chawla, H.M.</creatorcontrib><creatorcontrib>Ramakumar, K.L.</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Journal of hazardous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ramanjaneyulu, P.S.</au><au>Singh, Parminder</au><au>Sayi, Y.S.</au><au>Chawla, H.M.</au><au>Ramakumar, K.L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene</atitle><jtitle>Journal of hazardous materials</jtitle><addtitle>J Hazard Mater</addtitle><date>2010-03-15</date><risdate>2010</risdate><volume>175</volume><issue>1</issue><spage>1031</spage><epage>1036</epage><pages>1031-1036</pages><issn>0304-3894</issn><eissn>1873-3336</eissn><coden>JHMAD9</coden><abstract>A polyvinylchloride (PVC) based liquid membrane ion selective electrode (ISE) for cesium was fabricated with 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene as ionophore. Different membrane constituents were investigated to realise optimum performance of the ISE developed. Of the four plasticizers and two ion additives studied, the best response was observed with membrane having 2-nitro phenyl octyl ether (oNPOE) as plasticizer and potassium tetrakis (perchloro phenyl) borate (KTpClPB) as ion additive. Linear response over concentration range of 10 −5–10 −1 M CsCl was obtained. The Nernstian slope of the response was 56 mV per decade for Cs with a response time less than 20 s. Matched potential method has been applied to find out the selectivity for Cs over several ions like Rb +, K +, Na +, NH 4 +, Sr 2+, Ba 2+, Ca 2+, Mg 2+, Cu 2+, Pb 2+, Zn 2+, Ni 2+ and Ce 3+. The response of ISE for Cs + was fairly constant over the pH range of 3–11. The lifetime of the electrode is 9 months which is the longest life for any membrane-based Cs-ISE so far developed. The concentration of cesium in two simulated high level active waste streams was determined and results agreed well with those obtained independently employing atomic absorption spectrometry.</abstract><cop>Kidlington</cop><pub>Elsevier B.V</pub><pmid>19942345</pmid><doi>10.1016/j.jhazmat.2009.10.113</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0304-3894
ispartof Journal of hazardous materials, 2010-03, Vol.175 (1), p.1031-1036
issn 0304-3894
1873-3336
language eng
recordid cdi_proquest_miscellaneous_733926539
source MEDLINE; Elsevier ScienceDirect Journals
subjects Applied sciences
Calixarene azo compound
Calixarenes - chemistry
Cesium - chemistry
Cesium ion selective electrode
Chlorides - chemistry
Electrochemistry - methods
Exact sciences and technology
Hydrogen-Ion Concentration
Ion-Selective Electrodes
Ions
Membranes, Artificial
Phenols - chemistry
Plasticizers - chemistry
Pollution
Poly(vinyl chloride) membrane electrode
Polyvinyl Chloride - chemistry
Potentiometry
Radioactive Waste - analysis
Radioactive waste streams
Radioactive wastes
Rivers
Spectrophotometry, Atomic - methods
Wastes
Water Pollutants, Chemical - analysis
title Ion selective electrode for cesium based on 5-(4′-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix[4]arene
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-21T16%3A32%3A59IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ion%20selective%20electrode%20for%20cesium%20based%20on%205-(4%E2%80%B2-nitrophenylazo)25,27-bis(2-propyloxy)26,28-dihydroxycalix%5B4%5Darene&rft.jtitle=Journal%20of%20hazardous%20materials&rft.au=Ramanjaneyulu,%20P.S.&rft.date=2010-03-15&rft.volume=175&rft.issue=1&rft.spage=1031&rft.epage=1036&rft.pages=1031-1036&rft.issn=0304-3894&rft.eissn=1873-3336&rft.coden=JHMAD9&rft_id=info:doi/10.1016/j.jhazmat.2009.10.113&rft_dat=%3Cproquest_cross%3E733926539%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=733926539&rft_id=info:pmid/19942345&rft_els_id=S0304389409017646&rfr_iscdi=true