A Promising Approach to the Synthesis of 3D Nanoporous Graphitic Carbon as a Unique Electrocatalyst Support for Methanol Oxidation
A 3D nanoporous graphitic carbon (g‐C) material is synthesized by using an adamantane (C10H16) flame, and utilized to support a Pt50–Ru50 alloy catalyst. The physico‐chemical properties of the Pt50–Ru50/3D nanoporous g‐C electrode are examined by a range of spectroscopy techniques as well as Brunaue...
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| Veröffentlicht in: | ChemSusChem 2010-04, Vol.3 (4), p.460-466 |
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| creator | Tiwari, Jitendra N. Tiwari, Rajanish N. Chang, Yun-Min Lin, Kun-Lin |
| description | A 3D nanoporous graphitic carbon (g‐C) material is synthesized by using an adamantane (C10H16) flame, and utilized to support a Pt50–Ru50 alloy catalyst. The physico‐chemical properties of the Pt50–Ru50/3D nanoporous g‐C electrode are examined by a range of spectroscopy techniques as well as Brunauer–Emmett–Teller surface area analysis. Cyclic voltammetry measurements are used for electrochemical characterization of the Pt50–Ru50/3D nanoporous g‐C electrode. The electrochemical investigations show that the supported Pt50–Ru50 has excellent activity and stability towards methanol electro‐oxidation. Good CO tolerance is also shown, and considered to be due to the presence of Ru nanoparticles. It is proposed that Ru is able to promote the oxidation of strongly adsorbed CO on Pt by supplying an oxygen source: Ru(OH)ad. Moreover, the presence of 3D nanopores in the g‐C support may also contribute to the observed higher current density by virtue of the easy transport of methanol and the oxidation products through these nanopores.
3D nanoporous graphitic carbon is synthesized by the adamantane flame method, and used to support a Pt50–Ru50 alloy catalyst. The material has a large surface area, and electrochemical measurements show that the supported alloy has an excellent catalytic activity and stability towards methanol electro‐oxidation, indicating the suitability of 3D nanoporous graphitic carbon as catalyst carrier for liquid‐feed fuel cells. |
| doi_str_mv | 10.1002/cssc.200900223 |
| format | Article |
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3D nanoporous graphitic carbon is synthesized by the adamantane flame method, and used to support a Pt50–Ru50 alloy catalyst. The material has a large surface area, and electrochemical measurements show that the supported alloy has an excellent catalytic activity and stability towards methanol electro‐oxidation, indicating the suitability of 3D nanoporous graphitic carbon as catalyst carrier for liquid‐feed fuel cells.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.200900223</identifier><identifier>PMID: 20101666</identifier><language>eng</language><publisher>Weinheim: WILEY-VCH Verlag</publisher><subject>Alloys - chemistry ; carbon ; Catalysis ; Electrochemistry ; fuel cells ; Graphite - chemistry ; Methanol - chemistry ; methanol oxidation ; Microscopy, Electron, Scanning ; nanoporous materials ; Nanostructures - chemistry ; Oxidation-Reduction ; Photoelectron Spectroscopy ; Platinum - chemistry ; Porosity ; Ruthenium - chemistry ; supported catalysts ; Temperature</subject><ispartof>ChemSusChem, 2010-04, Vol.3 (4), p.460-466</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4853-98aa7d98a1e63eab512b4073220446410d521c6e4b9146237727f31fc69248a33</citedby><cites>FETCH-LOGICAL-c4853-98aa7d98a1e63eab512b4073220446410d521c6e4b9146237727f31fc69248a33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcssc.200900223$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcssc.200900223$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20101666$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Tiwari, Jitendra N.</creatorcontrib><creatorcontrib>Tiwari, Rajanish N.</creatorcontrib><creatorcontrib>Chang, Yun-Min</creatorcontrib><creatorcontrib>Lin, Kun-Lin</creatorcontrib><title>A Promising Approach to the Synthesis of 3D Nanoporous Graphitic Carbon as a Unique Electrocatalyst Support for Methanol Oxidation</title><title>ChemSusChem</title><addtitle>ChemSusChem</addtitle><description>A 3D nanoporous graphitic carbon (g‐C) material is synthesized by using an adamantane (C10H16) flame, and utilized to support a Pt50–Ru50 alloy catalyst. The physico‐chemical properties of the Pt50–Ru50/3D nanoporous g‐C electrode are examined by a range of spectroscopy techniques as well as Brunauer–Emmett–Teller surface area analysis. Cyclic voltammetry measurements are used for electrochemical characterization of the Pt50–Ru50/3D nanoporous g‐C electrode. The electrochemical investigations show that the supported Pt50–Ru50 has excellent activity and stability towards methanol electro‐oxidation. Good CO tolerance is also shown, and considered to be due to the presence of Ru nanoparticles. It is proposed that Ru is able to promote the oxidation of strongly adsorbed CO on Pt by supplying an oxygen source: Ru(OH)ad. Moreover, the presence of 3D nanopores in the g‐C support may also contribute to the observed higher current density by virtue of the easy transport of methanol and the oxidation products through these nanopores.
3D nanoporous graphitic carbon is synthesized by the adamantane flame method, and used to support a Pt50–Ru50 alloy catalyst. The material has a large surface area, and electrochemical measurements show that the supported alloy has an excellent catalytic activity and stability towards methanol electro‐oxidation, indicating the suitability of 3D nanoporous graphitic carbon as catalyst carrier for liquid‐feed fuel cells.</description><subject>Alloys - chemistry</subject><subject>carbon</subject><subject>Catalysis</subject><subject>Electrochemistry</subject><subject>fuel cells</subject><subject>Graphite - chemistry</subject><subject>Methanol - chemistry</subject><subject>methanol oxidation</subject><subject>Microscopy, Electron, Scanning</subject><subject>nanoporous materials</subject><subject>Nanostructures - chemistry</subject><subject>Oxidation-Reduction</subject><subject>Photoelectron Spectroscopy</subject><subject>Platinum - chemistry</subject><subject>Porosity</subject><subject>Ruthenium - chemistry</subject><subject>supported catalysts</subject><subject>Temperature</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkEtPGzEUha2qVXm02y7R3bGa1O-ZWUYDDVUpIFJU1I3lcTzEMBlPbUclW355jUIjdt3cey2d88nnIPSJ4AnBmH42MZoJxbjOD8reoH1SSV4IyW_f7m5G9tBBjPcYS1xL-R7tUUwwkVLuo6cpXAW_ctENdzAdx-C1WULykJYW5pshr-gi-A7YCVzowY8--HWEWdDj0iVnoNGh9QPoCBpuBvd7beG0tyYFb3TS_SYmmK_HbEvQ-QDfbVpmTA-Xj26hk_PDB_Su0320H1_2Ibr5cvqjOSvOL2dfm-l5YXglWFFXWpeLPImVzOpWENpyXDJKMeeSE7wQlBhpeVsTLikrS1p2jHRG1pRXmrFDdLzl5pD5lzGpHNvYvteDzZFUyViNheBVVk62ShN8jMF2agxupcNGEayea1fPtatd7dlw9IJetyu72Mn_9ZwF9Vbwx_V28x-caubz5jW82HpdTPZx59XhQcmSlUL9vJgp8etWkPr6mxLsL_8Gnhg</recordid><startdate>20100426</startdate><enddate>20100426</enddate><creator>Tiwari, Jitendra N.</creator><creator>Tiwari, Rajanish N.</creator><creator>Chang, Yun-Min</creator><creator>Lin, Kun-Lin</creator><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>BSCLL</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>20100426</creationdate><title>A Promising Approach to the Synthesis of 3D Nanoporous Graphitic Carbon as a Unique Electrocatalyst Support for Methanol Oxidation</title><author>Tiwari, Jitendra N. ; Tiwari, Rajanish N. ; Chang, Yun-Min ; Lin, Kun-Lin</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4853-98aa7d98a1e63eab512b4073220446410d521c6e4b9146237727f31fc69248a33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Alloys - chemistry</topic><topic>carbon</topic><topic>Catalysis</topic><topic>Electrochemistry</topic><topic>fuel cells</topic><topic>Graphite - chemistry</topic><topic>Methanol - chemistry</topic><topic>methanol oxidation</topic><topic>Microscopy, Electron, Scanning</topic><topic>nanoporous materials</topic><topic>Nanostructures - chemistry</topic><topic>Oxidation-Reduction</topic><topic>Photoelectron Spectroscopy</topic><topic>Platinum - chemistry</topic><topic>Porosity</topic><topic>Ruthenium - chemistry</topic><topic>supported catalysts</topic><topic>Temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Tiwari, Jitendra N.</creatorcontrib><creatorcontrib>Tiwari, Rajanish N.</creatorcontrib><creatorcontrib>Chang, Yun-Min</creatorcontrib><creatorcontrib>Lin, Kun-Lin</creatorcontrib><collection>Istex</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Tiwari, Jitendra N.</au><au>Tiwari, Rajanish N.</au><au>Chang, Yun-Min</au><au>Lin, Kun-Lin</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Promising Approach to the Synthesis of 3D Nanoporous Graphitic Carbon as a Unique Electrocatalyst Support for Methanol Oxidation</atitle><jtitle>ChemSusChem</jtitle><addtitle>ChemSusChem</addtitle><date>2010-04-26</date><risdate>2010</risdate><volume>3</volume><issue>4</issue><spage>460</spage><epage>466</epage><pages>460-466</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>A 3D nanoporous graphitic carbon (g‐C) material is synthesized by using an adamantane (C10H16) flame, and utilized to support a Pt50–Ru50 alloy catalyst. The physico‐chemical properties of the Pt50–Ru50/3D nanoporous g‐C electrode are examined by a range of spectroscopy techniques as well as Brunauer–Emmett–Teller surface area analysis. Cyclic voltammetry measurements are used for electrochemical characterization of the Pt50–Ru50/3D nanoporous g‐C electrode. The electrochemical investigations show that the supported Pt50–Ru50 has excellent activity and stability towards methanol electro‐oxidation. Good CO tolerance is also shown, and considered to be due to the presence of Ru nanoparticles. It is proposed that Ru is able to promote the oxidation of strongly adsorbed CO on Pt by supplying an oxygen source: Ru(OH)ad. Moreover, the presence of 3D nanopores in the g‐C support may also contribute to the observed higher current density by virtue of the easy transport of methanol and the oxidation products through these nanopores.
3D nanoporous graphitic carbon is synthesized by the adamantane flame method, and used to support a Pt50–Ru50 alloy catalyst. The material has a large surface area, and electrochemical measurements show that the supported alloy has an excellent catalytic activity and stability towards methanol electro‐oxidation, indicating the suitability of 3D nanoporous graphitic carbon as catalyst carrier for liquid‐feed fuel cells.</abstract><cop>Weinheim</cop><pub>WILEY-VCH Verlag</pub><pmid>20101666</pmid><doi>10.1002/cssc.200900223</doi><tpages>7</tpages></addata></record> |
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| subjects | Alloys - chemistry carbon Catalysis Electrochemistry fuel cells Graphite - chemistry Methanol - chemistry methanol oxidation Microscopy, Electron, Scanning nanoporous materials Nanostructures - chemistry Oxidation-Reduction Photoelectron Spectroscopy Platinum - chemistry Porosity Ruthenium - chemistry supported catalysts Temperature |
| title | A Promising Approach to the Synthesis of 3D Nanoporous Graphitic Carbon as a Unique Electrocatalyst Support for Methanol Oxidation |
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