Effects of Partial Confinement on the Specificity of Monomolecular Alkane Reactions for Acid Sites in Side Pockets of Mordenite

Catalytic specificity of side pockets: Monomolecular reactions with higher activation energies—dehydrogenation of linear alkanes (n‐butane: blue) and cracking of branched alkanes (isobutane: green)—show a stronger preference for acid sites located within eight‐membered ring (8‐MR) side pockets in mo...

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Veröffentlicht in:Angewandte Chemie (International ed.) 2010-01, Vol.49 (4), p.808-811
Hauptverfasser: Gounder, Rajamani, Iglesia, Enrique
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Sprache:eng
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