Experimental and theoretical characterization of molecular complexes formed between OCS and XY molecules (X, Y = F, Cl and Br) and their role in photochemical matrix reactions

Molecular complexes between OCS and ClF, Cl(2), Br(2), or BrCl have for the first time been isolated in solid matrixes at low temperature, and characterized by their IR spectra. 1 : 1 adducts between OCS and ClF, Cl(2), or BrCl were formed by broad-band UV-visible photolysis of matrix-isolated FC(O)...

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Veröffentlicht in:	Physical chemistry chemical physics : PCCP 2010-01, Vol.12 (3), p.563-571
Hauptverfasser:	PICONE, A. Lorena, DELLA VEDOVA, Carlos O, WILLNER, Helge, DOWNS, Anthony J, ROMANO, Rosana M
Format:	Artikel
Sprache:	eng
Schlagworte:	Bromine - chemistry Chemistry Chlorine - chemistry Exact sciences and technology Fluorine - chemistry General and physical chemistry Halogens - chemistry Models, Molecular Molecular Conformation Photochemical Processes Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics) Quantum Theory Sulfur Oxides - chemistry
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