Synthesis and stereochemistry of occidenol, a 4,5-dihydrooxipin-containing sesquiterpene: a pericyclic approach

The first synthesis of occidenol (1), a 4,5-dihydrooxipin-containing sesquiterpene, is reported. The stereochemistry is corrected from that postulated by Tomita and Hirose, by a synthesis starting with natural occidentalol (4), the stereochemistry of which was also initially in error. The route (sch...

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Veröffentlicht in:	Natural product communications 2010-01, Vol.5 (1), p.5-8
Hauptverfasser:	Marx, John N, Ajlouni, Abdulaziz
Format:	Artikel
Sprache:	eng
Schlagworte:	Molecular Structure Sesquiterpenes - chemical synthesis Stereoisomerism Thuja - chemistry
Online-Zugang:	Volltext
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