Time-resolved photoelectron spectroscopy of wavepackets through a conical intersection in NO2

Time-resolved photoelectron spectroscopy of wavepackets through a conical intersection in NO2

We report the results of theoretical studies of the time-resolved femtosecond photoelectron spectroscopy of quantum wavepackets through the conical intersection between the first two (2)A' states of NO(2). The Hamiltonian explicitly includes the pump-pulse interaction, the nonadiabatic coupling...

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Veröffentlicht in:The Journal of chemical physics 2010-03, Vol.132 (12), p.124307-124307
Hauptverfasser: Arasaki, Yasuki, Takatsuka, Kazuo, Wang, Kwanghsi, McKoy, Vincent
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container_title The Journal of chemical physics
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creator Arasaki, Yasuki
Takatsuka, Kazuo
Wang, Kwanghsi
McKoy, Vincent
description We report the results of theoretical studies of the time-resolved femtosecond photoelectron spectroscopy of quantum wavepackets through the conical intersection between the first two (2)A' states of NO(2). The Hamiltonian explicitly includes the pump-pulse interaction, the nonadiabatic coupling due to the conical intersection between the neutral states, and the probe interaction between the neutral states and discretized photoelectron continua. Geometry- and energy-dependent photoionization matrix elements are explicitly incorporated in these studies. Photoelectron angular distributions are seen to provide a clearer picture of the ionization channels and underlying wavepacket dynamics around the conical intersection than energy-resolved spectra. Time-resolved photoelectron velocity map images are also presented.
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title Time-resolved photoelectron spectroscopy of wavepackets through a conical intersection in NO2
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