Lead selective lipophilic acyclic diionizable polyethers

A structural series of acyclic polyether dicarboxylic acids with n-butyl and n-tetradecyl alkyl side chains at the α-position of the carboxylic acid units, as well as varying lengths of the ethylene glycol ether linkage connecting two benzo units were prepared. In terms of stability constants, compe...

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Veröffentlicht in:Talanta (Oxford) 1999-06, Vol.49 (1), p.69-75
Hauptverfasser: Kim, Jong Seung, Hwan Cho, Moon, Chul Lee, Sang, Hyun Pang, Jin, Hae Lee, Joung, Ohki, Akira
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container_issue 1
container_start_page 69
container_title Talanta (Oxford)
container_volume 49
creator Kim, Jong Seung
Hwan Cho, Moon
Chul Lee, Sang
Hyun Pang, Jin
Hae Lee, Joung
Ohki, Akira
description A structural series of acyclic polyether dicarboxylic acids with n-butyl and n-tetradecyl alkyl side chains at the α-position of the carboxylic acid units, as well as varying lengths of the ethylene glycol ether linkage connecting two benzo units were prepared. In terms of stability constants, competitive solvent extraction and cation transport experiment by bulk liquid membrane toward transition metal ions, ligand 3 with a monoethylene glycol unit and n-butyl side chains provide the best selectivity for the lead ion.
doi_str_mv 10.1016/S0039-9140(98)00362-2
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subjects Applied sciences
Chemistry
Coordination compounds
Exact sciences and technology
Inorganic chemistry and origins of life
Liquid membrane
Podand
Pollution
Preparations and properties
Selective complexation
Solvent extraction
Wastes
title Lead selective lipophilic acyclic diionizable polyethers
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