On the determination of the free concentration of ligands
Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of...
Gespeichert in:
Veröffentlicht in: | Talanta (Oxford) 1992-06, Vol.39 (6), p.649-652 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 652 |
---|---|
container_issue | 6 |
container_start_page | 649 |
container_title | Talanta (Oxford) |
container_volume | 39 |
creator | Placeres, J.C.Rodriguez Alaejos, M.T.Sanz Montelongo, F.J.Garcia |
description | Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of co-ordination systems. |
doi_str_mv | 10.1016/0039-9140(92)80075-O |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_733829357</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>003991409280075O</els_id><sourcerecordid>733829357</sourcerecordid><originalsourceid>FETCH-LOGICAL-c390t-d89be1dec8284401001e813ebf3843eeef16940536a4e75ef33e73c580dc95593</originalsourceid><addsrcrecordid>eNp9kEtLxDAQgIMo7rr6D0T2IKiH6qTTtMlFkMUXLPSi55BNpxrpQ5Ou4L-33S3rzdPAzDevj7FTDtcceHoDgCpSPIFLFV9JgExE-R6bcplhhCLDfTbdIRN2FMIHAMQIeMgmXKpUJMinTOXNvHuneUEd-do1pnNtM2_LTbL0RHPbNpaazu8qlXszTRGO2UFpqkAnY5yx14f7l8VTtMwfnxd3y8iigi4qpFoRL8jKWCYJcABOkiOtSpQJElHJU5WAwNQklAkqESlDKyQUVgmhcMYutnM_ffu1ptDp2gVLVWUaatdBZ4gyVsPHM5ZsSevbEDyV-tO72vgfzUEPzvQgRA9CtIr1xpnO-7azccF6VVPx1zRK6oHzETDBmqr0prEu7DjR789gOPR2i1Fv49uR18E66uUVzpPtdNG6_w_5BTghhnQ</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733829357</pqid></control><display><type>article</type><title>On the determination of the free concentration of ligands</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Placeres, J.C.Rodriguez ; Alaejos, M.T.Sanz ; Montelongo, F.J.Garcia</creator><creatorcontrib>Placeres, J.C.Rodriguez ; Alaejos, M.T.Sanz ; Montelongo, F.J.Garcia</creatorcontrib><description>Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of co-ordination systems.</description><identifier>ISSN: 0039-9140</identifier><identifier>EISSN: 1873-3573</identifier><identifier>DOI: 10.1016/0039-9140(92)80075-O</identifier><identifier>PMID: 18965431</identifier><identifier>CODEN: TLNTA2</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Chemistry ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Kinetics and mechanism of reactions</subject><ispartof>Talanta (Oxford), 1992-06, Vol.39 (6), p.649-652</ispartof><rights>1992</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c390t-d89be1dec8284401001e813ebf3843eeef16940536a4e75ef33e73c580dc95593</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/003991409280075O$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5382709$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/18965431$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Placeres, J.C.Rodriguez</creatorcontrib><creatorcontrib>Alaejos, M.T.Sanz</creatorcontrib><creatorcontrib>Montelongo, F.J.Garcia</creatorcontrib><title>On the determination of the free concentration of ligands</title><title>Talanta (Oxford)</title><addtitle>Talanta</addtitle><description>Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of co-ordination systems.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Kinetics and mechanism of reactions</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLxDAQgIMo7rr6D0T2IKiH6qTTtMlFkMUXLPSi55BNpxrpQ5Ou4L-33S3rzdPAzDevj7FTDtcceHoDgCpSPIFLFV9JgExE-R6bcplhhCLDfTbdIRN2FMIHAMQIeMgmXKpUJMinTOXNvHuneUEd-do1pnNtM2_LTbL0RHPbNpaazu8qlXszTRGO2UFpqkAnY5yx14f7l8VTtMwfnxd3y8iigi4qpFoRL8jKWCYJcABOkiOtSpQJElHJU5WAwNQklAkqESlDKyQUVgmhcMYutnM_ffu1ptDp2gVLVWUaatdBZ4gyVsPHM5ZsSevbEDyV-tO72vgfzUEPzvQgRA9CtIr1xpnO-7azccF6VVPx1zRK6oHzETDBmqr0prEu7DjR789gOPR2i1Fv49uR18E66uUVzpPtdNG6_w_5BTghhnQ</recordid><startdate>19920601</startdate><enddate>19920601</enddate><creator>Placeres, J.C.Rodriguez</creator><creator>Alaejos, M.T.Sanz</creator><creator>Montelongo, F.J.Garcia</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19920601</creationdate><title>On the determination of the free concentration of ligands</title><author>Placeres, J.C.Rodriguez ; Alaejos, M.T.Sanz ; Montelongo, F.J.Garcia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c390t-d89be1dec8284401001e813ebf3843eeef16940536a4e75ef33e73c580dc95593</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Kinetics and mechanism of reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Placeres, J.C.Rodriguez</creatorcontrib><creatorcontrib>Alaejos, M.T.Sanz</creatorcontrib><creatorcontrib>Montelongo, F.J.Garcia</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Placeres, J.C.Rodriguez</au><au>Alaejos, M.T.Sanz</au><au>Montelongo, F.J.Garcia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>On the determination of the free concentration of ligands</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>1992-06-01</date><risdate>1992</risdate><volume>39</volume><issue>6</issue><spage>649</spage><epage>652</epage><pages>649-652</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>Working with a sufficient excess of any of the protonated forms of a ligand is shown to guarantee the validity of the determination of its free concentration when calculated by disregarding complexing effect. This result significantly extends the possibilities of studying the stability constants of co-ordination systems.</abstract><cop>Amsterdam</cop><cop>Oxford</cop><pub>Elsevier B.V</pub><pmid>18965431</pmid><doi>10.1016/0039-9140(92)80075-O</doi><tpages>4</tpages></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0039-9140 |
ispartof | Talanta (Oxford), 1992-06, Vol.39 (6), p.649-652 |
issn | 0039-9140 1873-3573 |
language | eng |
recordid | cdi_proquest_miscellaneous_733829357 |
source | ScienceDirect Journals (5 years ago - present) |
subjects | Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions |
title | On the determination of the free concentration of ligands |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-02T21%3A26%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=On%20the%20determination%20of%20the%20free%20concentration%20of%20ligands&rft.jtitle=Talanta%20(Oxford)&rft.au=Placeres,%20J.C.Rodriguez&rft.date=1992-06-01&rft.volume=39&rft.issue=6&rft.spage=649&rft.epage=652&rft.pages=649-652&rft.issn=0039-9140&rft.eissn=1873-3573&rft.coden=TLNTA2&rft_id=info:doi/10.1016/0039-9140(92)80075-O&rft_dat=%3Cproquest_cross%3E733829357%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=733829357&rft_id=info:pmid/18965431&rft_els_id=003991409280075O&rfr_iscdi=true |