Effect of ionic strength on the formal potential of the glass electrode in various saline media

Effect of ionic strength on the formal potential of the glass electrode in various saline media

We examined the variation with ionic strength (I, adjusted with KCl, KNO(3), KBr, NaCl or NaClO(4)) of the formal potential (E(const)) for glass electrodes exhibiting a Nernstian response (i.e. E(cell)=E(const)-slog[H(+)]). For this purpose, we investigated the different factors included in the form...

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Veröffentlicht in:Talanta (Oxford) 1998-08, Vol.46 (6), p.1469-1477
Hauptverfasser: BRANDARIZ, I, VILARINO, T, ALONSO, P, HERRERO, R, FIOL, S, SASTRE DE VICENTE, M. E
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Ion selective electrodes
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container_end_page 1477
container_issue 6
container_start_page 1469
container_title Talanta (Oxford)
container_volume 46
creator BRANDARIZ, I
VILARINO, T
ALONSO, P
HERRERO, R
FIOL, S
SASTRE DE VICENTE, M. E
description We examined the variation with ionic strength (I, adjusted with KCl, KNO(3), KBr, NaCl or NaClO(4)) of the formal potential (E(const)) for glass electrodes exhibiting a Nernstian response (i.e. E(cell)=E(const)-slog[H(+)]). For this purpose, we investigated the different factors included in the formal potential, so we obtained reported values for the liquid junction potential as a function of ionic strength and determined the logarithm of the activity coefficient for the proton in various saline media, using Pitzer equations.
doi_str_mv 10.1016/S0039-9140(98)00022-8
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subjects Chemistry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Ion selective electrodes
title Effect of ionic strength on the formal potential of the glass electrode in various saline media
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