Complexation and fluorescence behavior of diazacrown ether carrying two anthryl pendants

Photoinduced electron transfer (PET) fluoroionophores ( 1b, 2b) that consist of diazacrown and two 9-anthryl pendants show fluorescent enhancement with various guest salts. The diaza-12-crown-4 derivative ( 2b) exhibited Zn 2+ selectivity and in the presence of this cation the host fluorescence inte...

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Veröffentlicht in:Talanta (Oxford) 1999-06, Vol.49 (2), p.339-344
Hauptverfasser: Kubo, Kanji, Ishige, Ryoichi, Sakurai, Tadamitsu
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Ishige, Ryoichi
Sakurai, Tadamitsu
description Photoinduced electron transfer (PET) fluoroionophores ( 1b, 2b) that consist of diazacrown and two 9-anthryl pendants show fluorescent enhancement with various guest salts. The diaza-12-crown-4 derivative ( 2b) exhibited Zn 2+ selectivity and in the presence of this cation the host fluorescence intensity was increased by a factor of 182. The guest cation-induced fluorescence enhancement of 2b was larger than the diaza-18-crown-6 derivative ( 1b).
doi_str_mv 10.1016/S0039-9140(98)00380-4
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source Elsevier ScienceDirect Journals
subjects Analytical chemistry
Anthryl pendants
Chemistry
Diazacrown ether
Exact sciences and technology
Fluorescence
Fluoroionophores
Photoinduced electron transfer
Spectrometric and optical methods
title Complexation and fluorescence behavior of diazacrown ether carrying two anthryl pendants
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