An investigation into the sorption of benzoic acids by polyurethane membrane
The extraction mechanism of organic compounds by ether- and ester-type polyurethane membrane has been investigated through a detailed study of sorption of monobromobenzoic acids. The effects of solution concentration, extraction time, surface area, pH, salts, and temperature on extraction were studi...
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Veröffentlicht in: | Talanta (Oxford) 1998-11, Vol.47 (3), p.697-709 |
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description | The extraction mechanism of organic compounds by ether- and ester-type polyurethane membrane has been investigated through a detailed study of sorption of monobromobenzoic acids. The effects of solution concentration, extraction time, surface area, pH, salts, and temperature on extraction were studied. It was found that monobromobenzoic acids are extracted in their neutral form, and that the extraction is controlled primarily by the relative strength of intra- and intermolecular hydrogen bonding. The ether-type polyurethane membrane allows a more efficient removal of monobromobenzoic acids from solution than the ester-type membrane. The extraction of benzoic acids with the ether-type membrane decreases as the temperature increases. When the ester-type polyurethane membrane is used, an extraction maximum is observed at room temperature with a decrease in extraction at lower and higher temperatures. |
doi_str_mv | 10.1016/S0039-9140(98)00115-5 |
format | Article |
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The effects of solution concentration, extraction time, surface area, pH, salts, and temperature on extraction were studied. It was found that monobromobenzoic acids are extracted in their neutral form, and that the extraction is controlled primarily by the relative strength of intra- and intermolecular hydrogen bonding. The ether-type polyurethane membrane allows a more efficient removal of monobromobenzoic acids from solution than the ester-type membrane. The extraction of benzoic acids with the ether-type membrane decreases as the temperature increases. 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When the ester-type polyurethane membrane is used, an extraction maximum is observed at room temperature with a decrease in extraction at lower and higher temperatures.</description><subject>Applied sciences</subject><subject>Benzoic acids</subject><subject>Chemical engineering</subject><subject>Exact sciences and technology</subject><subject>Exchange resins and membranes</subject><subject>Extraction mechanism</subject><subject>Forms of application and semi-finished materials</subject><subject>Industrial wastewaters</subject><subject>Membrane separation (reverse osmosis, dialysis...)</subject><subject>Pollution</subject><subject>Polymer industry, paints, wood</subject><subject>Polyurethane membrane</subject><subject>Technology of polymers</subject><subject>Wastewaters</subject><subject>Water treatment and pollution</subject><issn>0039-9140</issn><issn>1873-3573</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><recordid>eNqFkE1v1DAQhi0EotvCTwDlgEQ5pIw9ceycUFWVD2mlHoCz5ThjapTEi52ttPz6ej9Ujhwse6xnxq8fxt5wuOLA24_fAbCrO97AZac_AHAua_mMrbhWWKNU-JytnpAzdp7zbwAQCPiSnXHdtQpVs2Lr67kK8wPlJfyyS4j7aonVck9VjmlzuIm-6mn-G4OrrAtDrvpdtYnjbptoubczVRNNfSqHV-yFt2Om16f9gv38fPvj5mu9vvvy7eZ6XTvs-FL3rm1aJaWygMq22nPySouh1x5R-M6VQoJobSs59QBuEFpbidY3UBbHC_b-OHeT4p9tyW6mkB2NY8kQt9koRC20UFBIeSRdijkn8maTwmTTznAwe4_m4NHsJZlOm4NHI0vf29ML236i4V_XSVwB3p0Am50dffm-C_mJE43giPukn44YFR0PgZLJLtDsaAiJ3GKGGP6T5BG9DI6g</recordid><startdate>19981101</startdate><enddate>19981101</enddate><creator>Rzeszutek, Kathy</creator><creator>Chow, Art</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>IQODW</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope></search><sort><creationdate>19981101</creationdate><title>An investigation into the sorption of benzoic acids by polyurethane membrane</title><author>Rzeszutek, Kathy ; Chow, Art</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c391t-bc6467557a037a68f1ef782db8f332f9c7825026a651eb00cd288a53af40af413</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1998</creationdate><topic>Applied sciences</topic><topic>Benzoic acids</topic><topic>Chemical engineering</topic><topic>Exact sciences and technology</topic><topic>Exchange resins and membranes</topic><topic>Extraction mechanism</topic><topic>Forms of application and semi-finished materials</topic><topic>Industrial wastewaters</topic><topic>Membrane separation (reverse osmosis, dialysis...)</topic><topic>Pollution</topic><topic>Polymer industry, paints, wood</topic><topic>Polyurethane membrane</topic><topic>Technology of polymers</topic><topic>Wastewaters</topic><topic>Water treatment and pollution</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rzeszutek, Kathy</creatorcontrib><creatorcontrib>Chow, Art</creatorcontrib><collection>Pascal-Francis</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><jtitle>Talanta (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rzeszutek, Kathy</au><au>Chow, Art</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An investigation into the sorption of benzoic acids by polyurethane membrane</atitle><jtitle>Talanta (Oxford)</jtitle><addtitle>Talanta</addtitle><date>1998-11-01</date><risdate>1998</risdate><volume>47</volume><issue>3</issue><spage>697</spage><epage>709</epage><pages>697-709</pages><issn>0039-9140</issn><eissn>1873-3573</eissn><coden>TLNTA2</coden><abstract>The extraction mechanism of organic compounds by ether- and ester-type polyurethane membrane has been investigated through a detailed study of sorption of monobromobenzoic acids. The effects of solution concentration, extraction time, surface area, pH, salts, and temperature on extraction were studied. It was found that monobromobenzoic acids are extracted in their neutral form, and that the extraction is controlled primarily by the relative strength of intra- and intermolecular hydrogen bonding. The ether-type polyurethane membrane allows a more efficient removal of monobromobenzoic acids from solution than the ester-type membrane. The extraction of benzoic acids with the ether-type membrane decreases as the temperature increases. When the ester-type polyurethane membrane is used, an extraction maximum is observed at room temperature with a decrease in extraction at lower and higher temperatures.</abstract><cop>Amsterdam</cop><cop>Oxford</cop><pub>Elsevier B.V</pub><pmid>18967374</pmid><doi>10.1016/S0039-9140(98)00115-5</doi><tpages>13</tpages></addata></record> |
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subjects | Applied sciences Benzoic acids Chemical engineering Exact sciences and technology Exchange resins and membranes Extraction mechanism Forms of application and semi-finished materials Industrial wastewaters Membrane separation (reverse osmosis, dialysis...) Pollution Polymer industry, paints, wood Polyurethane membrane Technology of polymers Wastewaters Water treatment and pollution |
title | An investigation into the sorption of benzoic acids by polyurethane membrane |
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