Diffusion coefficients and complex equilibria in solution—II Approximate evaluation of formation constants

Diffusion coefficients and complex equilibria in solution—II Approximate evaluation of formation constants

It is shown, for four systems containing complexes of widely differing stabilities, that a very fair assessment of the values of formation constants is obtainable from the data pairs Δ i d log [X] (the pseudo-formation curve). This is seen as a preliminary exercise to the more precise analysis which...

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Veröffentlicht in:Talanta (Oxford) 1982-09, Vol.29 (9), p.739-742
1. Verfasser: Crow, D.R.
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description It is shown, for four systems containing complexes of widely differing stabilities, that a very fair assessment of the values of formation constants is obtainable from the data pairs Δ i d log [X] (the pseudo-formation curve). This is seen as a preliminary exercise to the more precise analysis which is possible in terms of mean diffusion coefficients which feature in equations reported earlier.
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title Diffusion coefficients and complex equilibria in solution—II Approximate evaluation of formation constants
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