Potentiometric determination of trace silver based on the use of a carbon paste electrode

A carbon paste electrode used as a sensor for silver has been developed and electrode response characteristics have been investigated. The electrode exhibits linear response to the logarithm of the concentration of silver from 5 × 10 −7 M to 1 × 10 −2 M, with a response slope of 63 ± 2 mV. The detec...

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Veröffentlicht in:Talanta (Oxford) 1991-10, Vol.38 (10), p.1185-1189
Hauptverfasser: Pei, Jianhong, Yin, Quan, Zhong, Jiayue
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creator Pei, Jianhong
Yin, Quan
Zhong, Jiayue
description A carbon paste electrode used as a sensor for silver has been developed and electrode response characteristics have been investigated. The electrode exhibits linear response to the logarithm of the concentration of silver from 5 × 10 −7 M to 1 × 10 −2 M, with a response slope of 63 ± 2 mV. The detection limit according to IUPAC recommendations is 1 × 10 −7 M. This electrode has been used to determine trace silver in fixing solutions and waste electroplate solutions with good results.
doi_str_mv 10.1016/0039-9140(91)80241-Q
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subjects Analytical chemistry
Chemistry
Electrochemical methods
Exact sciences and technology
title Potentiometric determination of trace silver based on the use of a carbon paste electrode
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