Novel oxidative ring opening reaction of H-isotelluro-chromenes to bis(o-formylstyryl) ditellurides
The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m-chloroperbenzoic acid (mCPBA) in CHCl3 resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-benzo...
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Veröffentlicht in: | Molecules (Basel, Switzerland) Switzerland), 2010-03, Vol.15 (3), p.1466-1472 |
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creator | Sashida, Haruki Satoh, Hirohito Ohyanagi, Kazuo Kaname, Mamoru |
description | The oxidation of 1-unsubstituted or 1-phenyl-1H-isotellurochromenes with m-chloroperbenzoic acid (mCPBA) in CHCl3 resulted in a ring opening reaction to produce as the sole products the corresponding o-formyl or benzoyl distyryl ditellurides, which were also produced by the hydrolysis of the 2-benzotelluropyrylium salts readily prepared from the parent isotellurochromene. |
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source | MDPI - Multidisciplinary Digital Publishing Institute; MEDLINE; DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central; Free Full-Text Journals in Chemistry |
subjects | Benzopyrans - chemistry Magnetic Resonance Spectroscopy Mass Spectrometry Spectrophotometry, Infrared Tellurium - chemistry |
title | Novel oxidative ring opening reaction of H-isotelluro-chromenes to bis(o-formylstyryl) ditellurides |
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