Attachment of Polybutadienes to Hydrogen-Terminated Silicon and Post-Derivatization of the Adsorbed Species

We report the first attachment of polymers with pendant vinyl groups to hydrogen-terminated silicon(111) (Si(111)-H); 1,2-polybutadiene (M w = 3200−3500 g/mol) was attached to Si(111)-H under mild conditions at room temperature with visible light. We also report the partial functionalization, in sol...

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Veröffentlicht in:	Langmuir 2010-02, Vol.26 (3), p.1923-1928
Hauptverfasser:	Wickard, Todd D, Nelsen, Emily, Madaan, Nitesh, ten Brummelhuis, Niels, Diehl, Christina, Schlaad, Helmut, Davis, Robert C, Linford, Matthew R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Interfaces: Adsorption, Reactions, Films, Forces Surface physical chemistry
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