Reactivity of a disilylene [{PhC(NBu(t))(2)}Si](2) toward bromine: synthesis and characterization of a stable monomeric bromosilylene
The reaction of the disilylene [{PhC(NBu(t))(2)}Si](2) (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBu(t))(2)}SiBr] (2). The result shows that the Si(I)-Si(I) bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined.
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| Veröffentlicht in: | Inorganic chemistry 2010-01, Vol.49 (2), p.371-373 |
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| container_end_page | 373 |
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| container_issue | 2 |
| container_start_page | 371 |
| container_title | Inorganic chemistry |
| container_volume | 49 |
| creator | Yeong, Hui-Xian Lau, Kai-Chung Xi, Hong-Wei Hwa Lim, Kok So, Cheuk-Wai |
| description | The reaction of the disilylene [{PhC(NBu(t))(2)}Si](2) (1) with 1 equiv of bromine in toluene afforded novel monomeric bromosilylene [{PhC(NBu(t))(2)}SiBr] (2). The result shows that the Si(I)-Si(I) bond in 1 was cleaved by bromine. An X-ray structure of compound 2 has been determined. |
| doi_str_mv | 10.1021/ic9021382 |
| format | Article |
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| fulltext | fulltext |
| identifier | EISSN: 1520-510X |
| ispartof | Inorganic chemistry, 2010-01, Vol.49 (2), p.371-373 |
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| source | MEDLINE; American Chemical Society Journals |
| subjects | Bromine - chemistry Models, Molecular Molecular Structure Organosilicon Compounds - chemistry |
| title | Reactivity of a disilylene [{PhC(NBu(t))(2)}Si](2) toward bromine: synthesis and characterization of a stable monomeric bromosilylene |
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