Nucleophilic Catalysis of Carbohydrate Oxime Formation by Anilines

Chemoselective formation of glycoconjugates from unprotected glycans is needed to further develop chemical biology involving glycans. Carbohydrate oxime formation is often slow, and organocatalysis by anilines would be highly promising. Here, we present that carbohydrate oxime formation can be catal...

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Veröffentlicht in:	Journal of organic chemistry 2010-03, Vol.75 (5), p.1752-1755
Hauptverfasser:	Thygesen, Mikkel B, Munch, Henrik, Sauer, Jørgen, Cló, Emiliano, Jørgensen, Malene R, Hindsgaul, Ole, Jensen, Knud J
Format:	Artikel
Sprache:	eng
Schlagworte:	Aniline Compounds - chemistry Carbohydrates - chemical synthesis Carbohydrates - chemistry Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Catalysis Chemistry Exact sciences and technology Glycoconjugates - chemical synthesis Glycoconjugates - chemistry Magnetic Resonance Spectroscopy Models, Chemical Molecular Sequence Data Molecular Structure Noncondensed benzenic compounds Organic chemistry Oximes - chemical synthesis Oximes - chemistry Polysaccharides - chemistry Preparations and properties
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