Stereoselective Phosphine-Catalyzed Synthesis of Highly Functionalized Diquinanes

Two rings to rule them all: A versatile method has been developed for the room‐temperature synthesis of diquinanes from acyclic precursors, thereby generating two rings, three stereocenters, and a double bond with high selectivity. The products of the double cyclization can be derivatized with excel...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 2010-01, Vol.49 (1), p.161-163
Hauptverfasser:	Wilson, Jonathan E, Sun, Jianwei, Fu, Gregory C
Format:	Artikel
Sprache:	eng
Schlagworte:	asymmetric synthesis Bridged Bicyclo Compounds - chemistry Catalysis Cyclization homogeneous catalysis organocatalysis phosphines Phosphines - chemistry Stereoisomerism
Online-Zugang:	Volltext
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