Stereoselective Phosphine-Catalyzed Synthesis of Highly Functionalized Diquinanes
Two rings to rule them all: A versatile method has been developed for the room‐temperature synthesis of diquinanes from acyclic precursors, thereby generating two rings, three stereocenters, and a double bond with high selectivity. The products of the double cyclization can be derivatized with excel...
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-01, Vol.49 (1), p.161-163 |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Wilson, Jonathan E Sun, Jianwei Fu, Gregory C |
| description | Two rings to rule them all: A versatile method has been developed for the room‐temperature synthesis of diquinanes from acyclic precursors, thereby generating two rings, three stereocenters, and a double bond with high selectivity. The products of the double cyclization can be derivatized with excellent diastereoselection into an array of highly functionalized compounds. |
| doi_str_mv | 10.1002/anie.200905125 |
| format | Article |
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| issn | 1433-7851 1521-3773 |
| language | eng |
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| source | MEDLINE; Wiley Journals |
| subjects | asymmetric synthesis Bridged Bicyclo Compounds - chemistry Catalysis Cyclization homogeneous catalysis organocatalysis phosphines Phosphines - chemistry Stereoisomerism |
| title | Stereoselective Phosphine-Catalyzed Synthesis of Highly Functionalized Diquinanes |
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