Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes

Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes

Intramolecular additions of amines to olefinic and acetylenic residues in the presence of B(C6F5)3 affords a “frustrated Lewis Pair” strategy to five‐ and six‐membered‐ring heterocyclic ammonium borate derivatives (see picture).

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Veröffentlicht in:Chemistry : a European journal 2010-03, Vol.16 (10), p.3005-3008
Hauptverfasser: Voss, Tanja, Chen, Chao, Kehr, Gerald, Nauha, Elisa, Erker, Gerhard, Stephan, Douglas W.
Format: Artikel
Sprache:eng
Schlagworte:
Alkynes
Amines
Borates
Chemistry
cyclic ammonium salts
cyclization
Derivatives
frustrated Lewis pairs
heterocycles
Lewis acid
Olefins
Residues
Strategy
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container_end_page 3008
container_issue 10
container_start_page 3005
container_title Chemistry : a European journal
container_volume 16
creator Voss, Tanja
Chen, Chao
Kehr, Gerald
Nauha, Elisa
Erker, Gerhard
Stephan, Douglas W.
description Intramolecular additions of amines to olefinic and acetylenic residues in the presence of B(C6F5)3 affords a “frustrated Lewis Pair” strategy to five‐ and six‐membered‐ring heterocyclic ammonium borate derivatives (see picture).
doi_str_mv 10.1002/chem.200903483
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source Wiley Online Library Journals Frontfile Complete
subjects Alkynes
Amines
Borates
Chemistry
cyclic ammonium salts
cyclization
Derivatives
frustrated Lewis pairs
heterocycles
Lewis acid
Olefins
Residues
Strategy
title Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes
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