Hydrogen-bonding patterns in two aroylthiocarbamates and two aroylimidothiocarbonates

Hydrogen-bonding patterns in two aroylthiocarbamates and two aroylimidothiocarbonates

In O‐ethyl N‐benzoylthiocarbamate, C10H11NO2S, the molecules are linked into sheets by a combination of two‐centre N—H...O and C—H...S hydrogen bonds and a three‐centre C—H...(O,S) hydrogen bond. A combination of two‐centre N—H...O and C—H...O hydrogen bonds links the molecules of O‐ethyl N‐(4‐methy...

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Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2010-03, Vol.66 (3), p.o141-o146
Hauptverfasser: Insuasty, Henry, Castro, Edison, Sánchez, Edison, Cobo, Justo, Glidewell, Christopher
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Carbon
Hydrogen bonds
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container_title Acta crystallographica. Section C, Crystal structure communications
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creator Insuasty, Henry
Castro, Edison
Sánchez, Edison
Cobo, Justo
Glidewell, Christopher
description In O‐ethyl N‐benzoylthiocarbamate, C10H11NO2S, the molecules are linked into sheets by a combination of two‐centre N—H...O and C—H...S hydrogen bonds and a three‐centre C—H...(O,S) hydrogen bond. A combination of two‐centre N—H...O and C—H...O hydrogen bonds links the molecules of O‐ethyl N‐(4‐methylbenzoyl)thiocarbamate, C11H13NO2S, into chains of rings, which are linked into sheets by an aromatic π–π stacking interaction. In O,S‐diethyl N‐(4‐methylbenzoyl)imidothiocarbonate, C13H17NO2S, pairs of molecules are linked into centrosymmetric dimers by pairs of symmetry‐related C—H...π(arene) hydrogen bonds, while the molecules of O,S‐diethyl N‐(4‐chlorobenzoyl)imidothiocarbonate, C12H14ClNO2S, are linked by a single C—H...O hydrogen bond into simple chains, pairs of which are linked by an aromatic π–π stacking interaction to form a ladder‐type structure.
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subjects Carbon
Hydrogen bonds
title Hydrogen-bonding patterns in two aroylthiocarbamates and two aroylimidothiocarbonates
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