Enantioselective nitroso aldol reaction catalyzed by QuinoxP.silver(I) complex and tin methoxide
A catalytic enantioselective O-nitroso aldol reaction of alkenyl trichloroacetates with nitrosoarenes was achieved using the (R,R)-t-Bu-QuinoxP*.AgOAc complex as the chiral catalyst and Bu(2)Sn(OMe)(2) as the achiral cocatalyst in the presence of methanol. Optically active alpha-aminooxy ketones wit...
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| Veröffentlicht in: | Journal of the American Chemical Society 2010-04, Vol.132 (15), p.5328-5329 |
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| container_end_page | 5329 |
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| container_issue | 15 |
| container_start_page | 5328 |
| container_title | Journal of the American Chemical Society |
| container_volume | 132 |
| creator | Yanagisawa, Akira Takeshita, Satoshi Izumi, Youhei Yoshida, Kazuhiro |
| description | A catalytic enantioselective O-nitroso aldol reaction of alkenyl trichloroacetates with nitrosoarenes was achieved using the (R,R)-t-Bu-QuinoxP*.AgOAc complex as the chiral catalyst and Bu(2)Sn(OMe)(2) as the achiral cocatalyst in the presence of methanol. Optically active alpha-aminooxy ketones with up to 99% ee were regioselectively obtained in high yields from various alkenyl trichloroacetates of cyclic ketones. |
| doi_str_mv | 10.1021/ja910588w |
| format | Article |
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Optically active alpha-aminooxy ketones with up to 99% ee were regioselectively obtained in high yields from various alkenyl trichloroacetates of cyclic ketones.</abstract><cop>United States</cop><pmid>20337442</pmid><doi>10.1021/ja910588w</doi><tpages>2</tpages></addata></record> |
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| language | eng |
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| source | ACS Publications |
| title | Enantioselective nitroso aldol reaction catalyzed by QuinoxP.silver(I) complex and tin methoxide |
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