New xanthate-based radical cyclization onto alkynes

To bypass the failure of radical cyclization involving a xanthate transfer on alkynes, a new reductive cyclization strategy has been completed with the use of a stoichiometric amount of dilauroyl peroxide in isopropanol. When the starting xanthates are prepared via a Ugi 4-component reaction with pr...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (14), p.2489-2491
Hauptverfasser: El Kaïm, Laurent, Grimaud, Laurence, Miranda, Luis D, Vieu, Emilie, Cano-Herrera, M-Angeles, Perez-Labrada, Karel
Format: Artikel
Sprache:eng
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