Structure and properties of alkali cobalt double oxides A(0.6)CoO(2) (A = Li, Na, and K)

Structure and properties of alkali cobalt double oxides A(0.6)CoO(2) (A = Li, Na, and K)

Lamellar A(x)CoO(2) cobalt double oxides with A = Li, Na, and K (x approximately 0.6) have been synthesized and their chemical (alkali content, oxidation state, and structure) and physical (resistivity, thermopower, magnetization, and specific heat) properties have been studied. All the three materi...

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Veröffentlicht in:Inorganic chemistry 2009-10, Vol.48 (20), p.9671-9683
Hauptverfasser: Pollet, Michaël, Blangero, Maxime, Doumerc, Jean-Pierre, Decourt, Rodolphe, Carlier, Dany, Denage, Catherine, Delmas, Claude
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container_end_page 9683
container_issue 20
container_start_page 9671
container_title Inorganic chemistry
container_volume 48
creator Pollet, Michaël
Blangero, Maxime
Doumerc, Jean-Pierre
Decourt, Rodolphe
Carlier, Dany
Denage, Catherine
Delmas, Claude
description Lamellar A(x)CoO(2) cobalt double oxides with A = Li, Na, and K (x approximately 0.6) have been synthesized and their chemical (alkali content, oxidation state, and structure) and physical (resistivity, thermopower, magnetization, and specific heat) properties have been studied. All the three materials exhibit strong electron correlation emphasized by their behavior ranging from Fermi liquid to spin-polarized system. Our results show that both the dimensionality of the interactions and the nature of the alkali play a determining role on the properties.
doi_str_mv 10.1021/ic900386q
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title Structure and properties of alkali cobalt double oxides A(0.6)CoO(2) (A = Li, Na, and K)
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