Inkless Microcontact Printing on SAMs of Boc- and TBS-Protected Thiols

We report a new inkless catalytic μCP technique that achieves accurate, fast, and complete pattern reproduction on SAMs of Boc- and TBS-protected thiols immobilized on gold using a polyurethane-acrylate stamp functionalized with covalently bound sulfonic acids. Pattern transfer is complete at room t...

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Veröffentlicht in:Nano letters 2010-01, Vol.10 (1), p.43-46
Hauptverfasser: Shestopalov, Alexander A, Clark, Robert L, Toone, Eric J
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creator Shestopalov, Alexander A
Clark, Robert L
Toone, Eric J
description We report a new inkless catalytic μCP technique that achieves accurate, fast, and complete pattern reproduction on SAMs of Boc- and TBS-protected thiols immobilized on gold using a polyurethane-acrylate stamp functionalized with covalently bound sulfonic acids. Pattern transfer is complete at room temperature just after one minute of contact and renders sub-200 nm size structures of chemically differentiated SAMs.
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subjects Acrylates - chemistry
Catalysis
Cross-disciplinary physics: materials science
rheology
DNA - chemistry
Exact sciences and technology
Materials science
Materials Testing
Metal Nanoparticles - chemistry
Methods of nanofabrication
Microscopy, Atomic Force - methods
Microscopy, Electron, Scanning - methods
Nanolithography
Nanotechnology - methods
Oxygen - chemistry
Physics
Polymers - chemistry
Polyurethanes - chemistry
Sulfhydryl Compounds - chemistry
Sulfonic Acids - chemistry
Surface Properties
Temperature
title Inkless Microcontact Printing on SAMs of Boc- and TBS-Protected Thiols
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