A chiral diphosphine as trans-chelate ligand and its relevance to catalysis
The chiral diphosphine ligand R,R-trans-1,2-C(6)H(10)(NHCOC(6)H(4)PPh(2))(2), 1, gives the fluxional trans-chelate complexes [M(1)]X, 2a-2c, M = Au or Ag. It is suggested that a similar trans-chelate conformation may be present in the catalytic intermediate [Pd(1)].
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2010-03, Vol.46 (11), p.1953-1955 |
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| container_end_page | 1955 |
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| container_issue | 11 |
| container_start_page | 1953 |
| container_title | Chemical communications (Cambridge, England) |
| container_volume | 46 |
| creator | Nasser, Nasser Eisler, Dana J Puddephatt, Richard J |
| description | The chiral diphosphine ligand R,R-trans-1,2-C(6)H(10)(NHCOC(6)H(4)PPh(2))(2), 1, gives the fluxional trans-chelate complexes [M(1)]X, 2a-2c, M = Au or Ag. It is suggested that a similar trans-chelate conformation may be present in the catalytic intermediate [Pd(1)]. |
| doi_str_mv | 10.1039/b923911a |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2010-03, Vol.46 (11), p.1953-1955 |
| issn | 1359-7345 1364-548X |
| language | eng |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| title | A chiral diphosphine as trans-chelate ligand and its relevance to catalysis |
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