Palladium-Catalyzed Reductive Homocoupling of Aromatic Halides and Oxidation of Alcohols

Palladium-catalyzed reductive homocoupling of aromatic halides can be performed in alcohol solutions without any auxiliary reducing reagents. Pd(dppf)Cl2 [dppf = 1,1′-bis(diphenylphosphino)ferrocene] has been shown as the most effective catalyst among the palladium catalysts screened for the model r...

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Veröffentlicht in:	Journal of organic chemistry 2010-04, Vol.75 (8), p.2556-2563
Hauptverfasser:	Zeng, Minfeng, Du, Yijun, Shao, Linjun, Qi, Chenze, Zhang, Xian-Man
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols - chemistry Catalysis Catalysts: preparations and properties Chemistry Exact sciences and technology General and physical chemistry Halogens - chemistry Hydrogen-Ion Concentration Iodobenzenes - chemistry Kinetics and mechanisms Noncondensed benzenic compounds Organic chemistry Organometallic Compounds - chemistry Oxidation-Reduction Palladium - chemistry Photoelectron Spectroscopy Preparations and properties Reactivity and mechanisms Solutions Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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