Direct Observation of Molecular-Level Template Action Leading to Self-Assembly of a Porous Framework

The molecular steps involved in the self‐assembly of Cu3(BTC)2 (BTC=1,3,5‐benzenetricarboxylic acid) metal–organic frameworks that enclose Keggin‐type H3PW12O40 heteropolyacid molecules were unraveled by using solution 17O, 31P, and 183W NMR spectroscopy, small‐angle X‐ray scattering, near‐IR spectr...

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Veröffentlicht in:	Chemistry : a European journal 2010-04, Vol.16 (13), p.3926-3932
Hauptverfasser:	Bajpe, Sneha R., Kirschhock, Christine E. A., Aerts, Alexander, Breynaert, Eric, Absillis, Gregory, Parac-Vogt, Tatjana N., Giebeler, Lars, Martens, Johan A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aqueous solutions Chemistry Complexation Copper - chemistry Formations Ions - chemistry Joining keggin heteropolyacids Lead (metal) Magnetic Resonance Spectroscopy metal-organic frameworks Metalorganic compounds Metals - chemistry Models, Molecular Nanostructure NMR spectroscopy Organometallic Compounds - chemistry polyoxometalates Porosity Self assembly Solutions Spectrophotometry, Ultraviolet Spectroscopy Spectrum analysis template synthesis Tungsten Compounds - chemistry
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