A new water-soluble copper(II) complex as a selective fluorescent sensor for azide ion
{[Cu(2)(H(2)L)(OH)(H(2)O)].(ClO(4))(2)(H(2)O)} (1) serves as a selective azide ion fluorescent sensor in aqueous medium. 1 binds with N(3)(-) to give [Cu(6)(HL)(2)(mu(1,1)-N(3))(6)] (2) which imposes rigidity and decreases the non-radiative decay of the excited state to give rise to fluorescent enha...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2010-01, Vol.46 (10), p.1754-1756 |
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| container_end_page | 1756 |
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| container_issue | 10 |
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| container_title | Chemical communications (Cambridge, England) |
| container_volume | 46 |
| creator | Dhara, Koushik Saha, Uday Chand Dan, Abhijit Sarkar, Sandipan Manassero, Mario Chattopadhyay, Pabitra |
| description | {[Cu(2)(H(2)L)(OH)(H(2)O)].(ClO(4))(2)(H(2)O)} (1) serves as a selective azide ion fluorescent sensor in aqueous medium. 1 binds with N(3)(-) to give [Cu(6)(HL)(2)(mu(1,1)-N(3))(6)] (2) which imposes rigidity and decreases the non-radiative decay of the excited state to give rise to fluorescent enhancement. 1 is highly selective over other various anions in aqueous medium. |
| doi_str_mv | 10.1039/b919937c |
| format | Article |
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| ispartof | Chemical communications (Cambridge, England), 2010-01, Vol.46 (10), p.1754-1756 |
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| source | MEDLINE; Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Anions Azides - analysis Coordination Complexes - chemistry Copper - chemistry COPPER COMPOUNDS Decay Excitation Fluorescent Dyes - chemistry Models, Molecular Molecular Conformation Organometallic Compounds - chemistry Rigidity Sensors Solubility Solutions Spectrometry, Fluorescence Temperature WATER Water - chemistry |
| title | A new water-soluble copper(II) complex as a selective fluorescent sensor for azide ion |
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