Tetra-ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki−Miyaura Couplings with a Diaminochlorophosphine Ligand

Tetra-ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki−Miyaura Couplings with a Diaminochlorophosphine Ligand

A palladium complex derived from a sterically hindered diaminochlorophosphine allowed for Suzuki−Miyaura cross-couplings of chloroarenes with ample scope and provided access to tetra-ortho-substituted bi(hetero)aryls.

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Veröffentlicht in:Organic letters 2010-03, Vol.12 (5), p.1004-1007
Hauptverfasser: Ackermann, Lutz, Potukuchi, Harish K, Althammer, Andreas, Born, Robert, Mayer, Peter
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container_end_page 1007
container_issue 5
container_start_page 1004
container_title Organic letters
container_volume 12
creator Ackermann, Lutz
Potukuchi, Harish K
Althammer, Andreas
Born, Robert
Mayer, Peter
description A palladium complex derived from a sterically hindered diaminochlorophosphine allowed for Suzuki−Miyaura cross-couplings of chloroarenes with ample scope and provided access to tetra-ortho-substituted bi(hetero)aryls.
doi_str_mv 10.1021/ol1000186
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title Tetra-ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki−Miyaura Couplings with a Diaminochlorophosphine Ligand
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