A Method for the Synthesis of Substituted Quinolines via Electrophilic Cyclization of 1-Azido-2-(2-propynyl)benzene

A new and efficient strategy for the synthesis of substituted quinolines via electrophilic cyclization is developed. The intramolecular cyclization of 1-azido-2-(2-propynyl)benzene 1 proceeds smoothly in the presence of electrophilic reagents (I2, Br2, ICl, NBS, NIS, and HNTf2) in CH3NO2 at room tem...

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Veröffentlicht in:	Journal of organic chemistry 2010-02, Vol.75 (4), p.1266-1270
Hauptverfasser:	Huo, Zhibao, Gridnev, Ilya D, Yamamoto, Yoshinori
Format:	Artikel
Sprache:	eng
Schlagworte:	Azides - chemistry Benzene Derivatives - chemistry Catalysis Catalysts: preparations and properties Chemistry Cyclization Electrons Exact sciences and technology General and physical chemistry Heterocyclic compounds Heterocyclic compounds with only one n hetero atom and condensed derivatives Indicators and Reagents - chemistry Molecular Structure Noncondensed benzenic compounds Organic chemistry Preparations and properties Quinolines - chemical synthesis Quinolines - chemistry Solvents - chemistry Stereoisomerism Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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