Application of prepared waterborne polyurethane extended with chitosan to impart antibacterial properties to acrylic fabrics
In this study, isophorone diisocyanate (IPDI), 2,2-bis (hydroxylmethyl)-propionic acid and polyethylene glycol (PEG) were employed to polymerize waterborne polyurethane. The polyurethane prepolymer was extended with chitosan of two different molecular weight (100,000 and 150,000), and used as finish...
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Veröffentlicht in: | Journal of materials science. Materials in medicine 2010-02, Vol.21 (2), p.507-514 |
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creator | Atef El-Sayed, A. El Gabry, L. K. Allam, O. G. |
description | In this study, isophorone diisocyanate (IPDI), 2,2-bis (hydroxylmethyl)-propionic acid and polyethylene glycol (PEG) were employed to polymerize waterborne polyurethane. The polyurethane prepolymer was extended with chitosan of two different molecular weight (100,000 and 150,000), and used as finishing agent for acrylic fabrics. The antibacterial activity of the acrylic fabric treated with the polyurethane-chitosan solution was improved even after 15 washing times. Pretreatment of acrylic fabrics with hydrazine hydrate was found to improve the uptake of the polymer by the fabric. The effects of hydrazine and polyurethane treatments on some of the inherent properties of acrylic were assessed. The functional groups of polyurethane prepolymer as well as polyurethane extended with chitosan were confirmed with the analysis of the spectra of Fourier transform infrared spectroscopy (FT-IR). |
doi_str_mv | 10.1007/s10856-009-3900-4 |
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The functional groups of polyurethane prepolymer as well as polyurethane extended with chitosan were confirmed with the analysis of the spectra of Fourier transform infrared spectroscopy (FT-IR).</description><identifier>ISSN: 0957-4530</identifier><identifier>EISSN: 1573-4838</identifier><identifier>DOI: 10.1007/s10856-009-3900-4</identifier><identifier>PMID: 19851844</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Acrylates - chemistry ; Acrylates - pharmacology ; Anti-Bacterial Agents - administration & dosage ; Anti-Bacterial Agents - chemistry ; Application fields ; Applied sciences ; Bacterial Physiological Phenomena - drug effects ; Biomaterials ; Biomedical Engineering and Bioengineering ; Biomedical materials ; Ceramics ; Chemistry and Materials Science ; Chitosan - chemistry ; Chitosan - pharmacology ; Composites ; Exact sciences and technology ; Fourier transforms ; Glass ; Materials Science ; Materials Testing ; Microbiology ; Natural Materials ; Organic polymers ; Physicochemistry of polymers ; Polyethylene glycol ; Polymer industry, paints, wood ; Polymer Sciences ; Polymerization ; Polyurethanes - chemistry ; Polyurethanes - pharmacology ; Regenerative Medicine/Tissue Engineering ; Surfaces and Interfaces ; Technology of polymers ; Thin Films ; Water - chemistry</subject><ispartof>Journal of materials science. 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K.</creatorcontrib><creatorcontrib>Allam, O. G.</creatorcontrib><title>Application of prepared waterborne polyurethane extended with chitosan to impart antibacterial properties to acrylic fabrics</title><title>Journal of materials science. Materials in medicine</title><addtitle>J Mater Sci: Mater Med</addtitle><addtitle>J Mater Sci Mater Med</addtitle><description>In this study, isophorone diisocyanate (IPDI), 2,2-bis (hydroxylmethyl)-propionic acid and polyethylene glycol (PEG) were employed to polymerize waterborne polyurethane. The polyurethane prepolymer was extended with chitosan of two different molecular weight (100,000 and 150,000), and used as finishing agent for acrylic fabrics. The antibacterial activity of the acrylic fabric treated with the polyurethane-chitosan solution was improved even after 15 washing times. Pretreatment of acrylic fabrics with hydrazine hydrate was found to improve the uptake of the polymer by the fabric. The effects of hydrazine and polyurethane treatments on some of the inherent properties of acrylic were assessed. The functional groups of polyurethane prepolymer as well as polyurethane extended with chitosan were confirmed with the analysis of the spectra of Fourier transform infrared spectroscopy (FT-IR).</description><subject>Acrylates - chemistry</subject><subject>Acrylates - pharmacology</subject><subject>Anti-Bacterial Agents - administration & dosage</subject><subject>Anti-Bacterial Agents - chemistry</subject><subject>Application fields</subject><subject>Applied sciences</subject><subject>Bacterial Physiological Phenomena - drug effects</subject><subject>Biomaterials</subject><subject>Biomedical Engineering and Bioengineering</subject><subject>Biomedical materials</subject><subject>Ceramics</subject><subject>Chemistry and Materials Science</subject><subject>Chitosan - chemistry</subject><subject>Chitosan - pharmacology</subject><subject>Composites</subject><subject>Exact sciences and technology</subject><subject>Fourier transforms</subject><subject>Glass</subject><subject>Materials Science</subject><subject>Materials Testing</subject><subject>Microbiology</subject><subject>Natural Materials</subject><subject>Organic polymers</subject><subject>Physicochemistry of polymers</subject><subject>Polyethylene glycol</subject><subject>Polymer industry, paints, wood</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polyurethanes - chemistry</subject><subject>Polyurethanes - pharmacology</subject><subject>Regenerative Medicine/Tissue Engineering</subject><subject>Surfaces and Interfaces</subject><subject>Technology of polymers</subject><subject>Thin Films</subject><subject>Water - chemistry</subject><issn>0957-4530</issn><issn>1573-4838</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>BENPR</sourceid><recordid>eNp1kU-L1TAUxYMozpvRD-BGgiCzqt40SZssh8F_MOBG1-E2TXwZ-pqapDgP_PCmvIcDgqsQ8jvnnptDyCsG7xhA_z4zULJrAHTDNUAjnpAdkz1vhOLqKdmBln0jJIcLcpnzPQAILeVzcsG0kkwJsSO_b5ZlChZLiDONni7JLZjcSH9hcWmIaXZ0idNxTa7ssV7cQ3HzuAGh7KndhxIzzrREGg5VWSjOJQxoqzrgVP3i4lIJLm8I2nSs06jHIQWbX5BnHqfsXp7PK_L944dvt5-bu6-fvtze3DVWAJQGkXlUoxQwMinB4ugGNQjBZdf6VkPXa9c6y_ygtRo962XbI9eeMy00V55fkeuTb03zc3W5mEPI1k1TXSiu2fScS8al7Cr55h_yPq5pruFM27L6ZZyJCrETZFPMOTlvlhQOmI6GgdmKMadiTC3GbMWYTfP6bLwOBzc-Ks5NVODtGcBscfIJZxvyX65tu74G7CvXnrhcn-YfLj0m_P_0PxD5p9E</recordid><startdate>20100201</startdate><enddate>20100201</enddate><creator>Atef El-Sayed, A.</creator><creator>El Gabry, L. 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Materials in medicine</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Atef El-Sayed, A.</au><au>El Gabry, L. K.</au><au>Allam, O. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Application of prepared waterborne polyurethane extended with chitosan to impart antibacterial properties to acrylic fabrics</atitle><jtitle>Journal of materials science. Materials in medicine</jtitle><stitle>J Mater Sci: Mater Med</stitle><addtitle>J Mater Sci Mater Med</addtitle><date>2010-02-01</date><risdate>2010</risdate><volume>21</volume><issue>2</issue><spage>507</spage><epage>514</epage><pages>507-514</pages><issn>0957-4530</issn><eissn>1573-4838</eissn><abstract>In this study, isophorone diisocyanate (IPDI), 2,2-bis (hydroxylmethyl)-propionic acid and polyethylene glycol (PEG) were employed to polymerize waterborne polyurethane. The polyurethane prepolymer was extended with chitosan of two different molecular weight (100,000 and 150,000), and used as finishing agent for acrylic fabrics. The antibacterial activity of the acrylic fabric treated with the polyurethane-chitosan solution was improved even after 15 washing times. Pretreatment of acrylic fabrics with hydrazine hydrate was found to improve the uptake of the polymer by the fabric. The effects of hydrazine and polyurethane treatments on some of the inherent properties of acrylic were assessed. The functional groups of polyurethane prepolymer as well as polyurethane extended with chitosan were confirmed with the analysis of the spectra of Fourier transform infrared spectroscopy (FT-IR).</abstract><cop>Boston</cop><pub>Springer US</pub><pmid>19851844</pmid><doi>10.1007/s10856-009-3900-4</doi><tpages>8</tpages></addata></record> |
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subjects | Acrylates - chemistry Acrylates - pharmacology Anti-Bacterial Agents - administration & dosage Anti-Bacterial Agents - chemistry Application fields Applied sciences Bacterial Physiological Phenomena - drug effects Biomaterials Biomedical Engineering and Bioengineering Biomedical materials Ceramics Chemistry and Materials Science Chitosan - chemistry Chitosan - pharmacology Composites Exact sciences and technology Fourier transforms Glass Materials Science Materials Testing Microbiology Natural Materials Organic polymers Physicochemistry of polymers Polyethylene glycol Polymer industry, paints, wood Polymer Sciences Polymerization Polyurethanes - chemistry Polyurethanes - pharmacology Regenerative Medicine/Tissue Engineering Surfaces and Interfaces Technology of polymers Thin Films Water - chemistry |
title | Application of prepared waterborne polyurethane extended with chitosan to impart antibacterial properties to acrylic fabrics |
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