Using Spin Dynamics of Covalently Linked Radical Ion Pairs To Probe the Impact of Structural and Energetic Changes on Charge Recombination

We have synthesized a series of structurally related, covalently linked electron donor−acceptor triads having highly restricted conformations to study the effects of radical ion pair (RP) structure, energetics, and solvation on charge recombination. The chromophoric electron acceptor in these triads...

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Veröffentlicht in:Journal of the American Chemical Society 2003-05, Vol.125 (21), p.6563-6572
Hauptverfasser: Shaakov, Shulamit, Galili, Tamar, Stavitski, Eli, Levanon, Haim, Lukas, Aaron, Wasielewski, Michael R
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Sprache:eng
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