Universal Iterative Strategy for the Divergent Synthesis of Dendritic Macromolecules from Conventional Monomers by a Combination of Living Radical Polymerization and Irreversible TERminator Multifunctional INItiator (TERMINI)

A new synthetic concept named TERMINI that stands for irreversible TERminator Multifunctional INItiator is reported. Suitable combinations of TERMINI and living polymerizations provide access to strategies for the design and synthesis of unprecedented complex molecular and macromolecular architectur...

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Veröffentlicht in:	Journal of the American Chemical Society 2003-05, Vol.125 (21), p.6503-6516
Hauptverfasser:	Percec, Virgil, Barboiu, Bogdan, Grigoras, Cristian, Bera, Tushar K
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymers with particular structures Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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