Octakis(3-azidopropyl)octasilsesquioxane: A Versatile Nanobuilding Block for the Efficient Preparation of Highly Functionalized Cube-Octameric Polyhedral Oligosilsesquioxane Frameworks Through Click Assembly

A one‐step synthesis of octakis(3‐azidopropyl)octasilsesquioxane from commercially available octakis(3‐aminopropyl)octasilsesquioxane has been developed through a highly efficient diazo‐transfer reaction under very mild conditions. Nonaflyl azide is shown to be a safer, cheaper, and more efficient r...

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Veröffentlicht in:Chemistry : a European journal 2010-03, Vol.16 (12), p.3833-3841
Hauptverfasser: Trastoy, Beatriz, Pérez-Ojeda, M. Eugenia, Sastre, Roberto, Chiara, Jose Luis
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Sprache:eng
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