An Acyclic Trialkylamine Virtually Planar at Nitrogen. Some Chemical Consequences of Nitrogen Planarity

The synthesis of the exceedingly congested amine tris(1,3-dihydroxy-2-propyl)amine, 9, was achieved in 47− 51% overall yield. The nitrogen atom of 9 is virtually planar; it is 0.082 Å out of the plane defined by the three attached carbons. The corresponding out-of-plane measurement is 0.282 Å for tr...

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Veröffentlicht in:	Journal of organic chemistry 2010-07, Vol.75 (13), p.4472-4479
Hauptverfasser:	Jie, Yuanping, Livant, Peter, Li, Hui, Yang, Minmin, Zhu, Wei, Cammarata, Vince, Almond, Philip, Sullens, Tyler, Qin, Yu, Bakker, Eric
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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