Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes
Come on allene: The [{RhCl(CO)2}2]‐ or [{RhCl(CO)dppp}2]‐catalyzed intramolecular [5+2] cycloaddition of alkyne‐allenylcyclopropanes under mild conditions affords the bicyclo[5.4.0]undecatriene or the larger bicyclo[5.5.0]dodecatriene frameworks (see scheme; dppp=1,3‐bis(diphenylphosphino)propane)....
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 2010-03, Vol.49 (12), p.2206-2210 |
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| container_title | Angewandte Chemie (International ed.) |
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| creator | Inagaki, Fuyuhiko Sugikubo, Katsuya Miyashita, Yusuke Mukai, Chisato |
| description | Come on allene: The [{RhCl(CO)2}2]‐ or [{RhCl(CO)dppp}2]‐catalyzed intramolecular [5+2] cycloaddition of alkyne‐allenylcyclopropanes under mild conditions affords the bicyclo[5.4.0]undecatriene or the larger bicyclo[5.5.0]dodecatriene frameworks (see scheme; dppp=1,3‐bis(diphenylphosphino)propane). |
| doi_str_mv | 10.1002/anie.200906994 |
| format | Article |
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| identifier | ISSN: 1433-7851 |
| ispartof | Angewandte Chemie (International ed.), 2010-03, Vol.49 (12), p.2206-2210 |
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| language | eng |
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| source | MEDLINE; Wiley Online Library All Journals |
| subjects | Alkadienes - chemistry Alkynes - chemistry allenes bicyclic compounds Bridged Bicyclo Compounds - chemistry Catalysis cycloaddition cyclopropanes Cyclopropanes - chemistry rhodium Rhodium - chemistry |
| title | Rhodium(I)-Catalyzed Intramolecular [5+2] Cycloaddition Reactions of Alkynes and Allenylcyclopropanes: Construction of Bicyclo[5.4.0]undecatrienes and Bicyclo[5.5.0]dodecatrienes |
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